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'Lewis Acid Base Adducts' in keywords Facet   Publication Year 1997  [X]
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1997[X]
1Author    Karl Hensen3, Frank Gebhardta, Michael BoltebRequires cookie*
 Title    Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole  
 Abstract    The bromosilanes RMe2SiBr (R = Me, Et, n-Pr and /-Pr) form ionic l:l-compounds with N-trimethylsilylimidazole (NTMSI), stable at room temperature. Crystals of the compounds with R = Et, n-Pr and i-Pr are obtained by sublimation. From the product of the reaction of 1,1-dibromosilacyclopentane with NTMSI single crystals of N,N'-bis(trimethylsilyl)imidazolium-bromide (R = Me) were obtained. In the new adducts both silicon atoms are tetracoordinated. 
  Reference    Z. Naturforsch. 52b, 1491—1496 (1997); eingegangen am 31. Juli 1997 
  Published    1997 
  Keywords    Alkyldimethylbromosilanes (alkyl = Me, Et, «-Pr and /-Pr), N-Trimethylsilylimidazole, Lewis-Acid-Base Adducts, Crystal Structure 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1491.pdf 
 Identifier    ZNB-1997-52b-1491 
 Volume    52