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2001 (1)
1Author    S. B. Gadzuric, I. J. Zsigrai, R. M. Nikolic3Requires cookie*
 Title    Thermodynamics of Lead(II) Halide Complex Formation in Calcium Nitrate Tetrahydrate -Acetamide Melts  
 Abstract    The complex formation between lead(II) ions and chloride and bromide ions in melts of C a(N 03) 2 • 4 H20 • aCH3CONH2 has been studied at different temperatures between 30 and 70 °C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from em f measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters A and A Sn for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts. 
  Reference    Z. Naturforsch. 56a, 832—836 (2001); received August 20 2001 
  Published    2001 
  Keywords    Lead(II) Halide Complexes, Acetamide, Calcium Nitrate Tetrahydrate 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0832.pdf 
 Identifier    ZNA-2001-56a-0832 
 Volume    56