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'Kinetics of Formation' in keywords Facet   Publication Year 1987  [X]
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1Author    MatthiasC. Hund, Arno Tißler, Peter Polanek, Martin Dräger, KlausK. UngerRequires cookie*
 Title    Zur Bildungskinetik des Zeolithen ZSM-11 On the Kinetics of Formation of the Zeolite ZSM-11  
 Abstract    The synthesis of pentasil ZSM-11 with Bu4N H S 0 4 as template was first optimized in a teflon-coated autoclave of 200 ml volume (163 °C, 3 days) and then transferred to a stirring autoclave of 1000 ml volume. The latter allowed sampling over the period of crystallization. Pure ZSM-11 crystallized at temperatures between 150 and 180 °C. In this range the induction period decreased from 15 to 2 hours while the rate of crystallization was enhanced from 2.5 to 5.6% per minute. From these values energies of activation for nucleation and crystallization were determined (99.8 and 43.4 kJ mol-1). 
  Reference    Z. Naturforsch. 42b, 1510—1514 (1987); eingegangen am 3. August 1987 
  Published    1987 
  Keywords    Zeolites ZSM-11, Synthesis, Kinetics of Formation 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-1510.pdf 
 Identifier    ZNB-1987-42b-1510 
 Volume    42