| | 1 | Author
| Roland Schmidt, Wolfgang Hiller, Gerhardt Pausewang | Requires cookie* | | | Title
| Peroxofluorokomplexe der Übergangsmetalle, V [1-3]  | | | | Abstract
| Kristallstruktur von K2Ti(02)F4 • H20 (orange) mit einem Di(/i-fluoro)diperoxo-hexafluorodititanat(IV)-Anion Transition Metal Peroxofluoro Complexes, V [1-3] Crystal Structure of K2Ti(02)F4 • HcO (orange) with a Di(J«-fluoro)diperoxo-hexafluorodititanate(IV) Anion Orange crystals of K2Ti(02)F4 ' H20 have been obtained from aqueous solution. The crystal structure (space group P2i/n, a = 604.3(3), b = 1424.6(4), c = 761.0(2) pm, ß = 103.98°, Z = 4, dc = 2.63 gem-3 , dm = 2.62 gem-3 , R = 0.051 for 2257 independent reflections) shows isolated di(ja-fluoro)-bridged [Ti2(02)2Fg] 4 -anions, which are inter-connected by hydrogen bonded H20 forming infinite chains. | | | |
Reference
| Z. Naturforsch. 38b, 849—851 (1983); eingegangen am 17. März 1983 | | | |
Published
| 1983 | | | |
Keywords
| K2Ti(02)F4 @BULLET H20, Crystal Structure, Preparation, Properties | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0849.pdf | | | | Identifier
| ZNB-1983-38b-0849 | | | | Volume
| 38 | |
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