| | 1 | Author
| Roswitha Schmidt, Rüdiger Kniep | Requires cookie* | | | Title
| Zn4Fe  | | | | Abstract
| ,15(P 0 4)6*4H 20 : Eine reduzierte und "aufgefüllte" Variante der Zn2(Z n,_xFeJ.)FeII,(P 0 4)3 • 2 H 20-Struktur Zn4FeH5(P 0 4)6-4 H 20 : A Reduced and "Filled" Variant of the Zn2(Z n ,_vF ev)Fem(P 0 4)3 • 2 H 20 Structure Single crystals o f Zn4F en5(P 0 4)6-4 H 20 were grown by hydrothermal treatment o f phospho-phyllite (Zn2F e(P 0 4)2-4 H 20)_ in H 20 at 180 °C. The crystal structure (tricl., P 1; a = 651.6(4) pm, b = 902.7(4) pm, c = 995.4(4) pm, a = 69.01(5)°, ß = 78.19(5)°, y = 75.33(5)°; Z = 1) can be derived from the Zn2(Z n,_vF ev)F eni(P0 4)3-2 H20 struc ture by reduction o f F e111 to F e11 and by filling a "structure hole" with an additional Fe11. | | | |
Reference
| Z. Naturforsch. 47b, 445 (1992); eingegangen am 23. September 1991 | | | |
Published
| 1992 | | | |
Keywords
| Orthophosphate o f Z n /F e11, Isotypic Relation, Preparation, Crystal Structure | | | |
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| default:Reihe_B/47/ZNB-1992-47b-0445_n.pdf | | | | Identifier
| ZNB-1992-47b-0445_n | | | | Volume
| 47 | |
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