| 1 | Author | Yoshio Kume, Tetsuo Asaji | Requires cookie* |
| Title | Chlorine-35 NQR Study of a Structural Phase Transition in (ND 4 ) 2 PdCV  | ||
| Abstract | Temperature dependences of 35 C1 NQR frequencies and spin-lattice relaxation times were measured at 4.2 to 400 K for natural and deuterated ammonium hexachloropalladate. It was confirmed that only the deuterated salt undergoes a first order phase transition at 30 K. The crystal structure of the low-tem-perature phase is predicted to be the same as that of the deuterated ammonium hexachloroplatinate and hexachloroplumbate. The mechanism of the deuteration-induced phase transition is discussed. | ||
| Reference | Z. Naturforsch. 53a, 514—517 (1998); received March 24 1998 | ||
| Published | 1998 | ||
| Keywords | Isotope Effect, Phase Transition, Chlorine NQR, Spin-lattice Relaxation, Deuterated Ammonium Hexachloropalladate | ||
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