| | 1 | Author
| Kristall, Achim Müller, Hartmut Bögge, Erich Krickemeyer, Gerald Henkel, Bernt Krebs | Requires cookie* | | | Title
| Isopoly-und Heteropoly-Thioanionen  | | | | Abstract
| -und Molekülstrukturen von (PPh4)2[(WS4)WS(WS4)], CS2[(WS4)W0(WS4)H20] 2 H20 und (AsPh4)2[(WS4)Ni(WS4)] Isopoly-and Heteropoly-Thioanions. Crystal and Molecular Structures of (PPh 4)2[(WS4)WS(WS4)]. Cs2[(WS4)W0(WS4)H20] • 2 H20 and (AsPh4)2[(WS4)Ni(WS4)] The crystal and molecular structures of (PPh4)2[(WS4)WS(WS4)] (LA) and CS2[(WS4)W0(WS4)H20] • 2 H20 (2 a), which contain the first reported isopoly-thioanion of a transition metal have been determined: la: (PI, a = 913.0(1), b = 1000.1(2), c = 1333.9(2) pm, a = 87.11(1), ß = 85.18(1), v = 83.07(1)°, V = 1277.0 • 10 6 pm 3 , Z = 1); ' 2a: (P2i/n, a = 071.0(2), b = 2018.5(4), c = 714.4(2) pm, ß = 101.42(2)°, V -949,3 • 10 6 pm 3 , Z = 2) and compared with that of the trimetallic heteropoly-thioanion of (AsPh4)2[(WS4)Ni(WS4)] (3a). 3a: (PI. a = 1255.2(3), b = 1277.1(3), c = 939.0(2) pm, a = 113.19(2), ß = 90.28(2), y = 108.72(2)°, V= 1201.5-10 6 pm 3 , Z = 1). Though there are delocalized orbitals in the isopoly-thioanions they can be regarded as coordination compounds of W IV X 2+ containing two W VI S4 2 ~ ligands. | | | |
Reference
| Z. Naturforsch. 37b, 1014 (1982); eingegangen am 6. April 1982 | | | |
Published
| 1982 | | | |
Keywords
| Crystal Structure, Isopoly-Thioanions, Heteropoly-Thioanions, Thiometalates, Mixed Valence Compounds | | | |
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| default:Reihe_B/37/ZNB-1982-37b-1014.pdf | | | | Identifier
| ZNB-1982-37b-1014 | | | | Volume
| 37 | |
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