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'Isoflavone' in keywords Facet   Publication Year 1982  [X]
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1982[X]
1Author    Ulrike Willeke, Wolfgang BarzRequires cookie*
 Title    Degradation of the Isoflavone Biochanin A by Fusarium javanicum  
 Abstract    After a lag-phase of 1 h a mycelial suspension of Fusarium javanicum completely degraded 5,7-dihydroxy-4'-methoxyisoflavone (biochanin A) to a series o f transiently accumulating catabolites. The compounds were elucidated by spectroscopic techniques and are arranged in the first known degradative pathway for an isoflavone: biochanin A -* dihydrobiochanin A -* 3-(/?-methoxyphenyl)-4,6-diketo-5,6-dihydro-4H-pyran -* />-methoxyphenylacetic acid -*■ p-hy-droxyphenylacetic acid -*■ 3,4-dihydroxyphenylacetic acid -*■ C 0 2. The carbon atoms o f bio­ chanin A not accounted for by this sequence are discussed in relation to microbial flavonoid pathways. 
  Reference    Z. Naturforsch. 37c, 861—8 (1982); received May 28 1982 
  Published    1982 
  Keywords    Isoflavone, Biochanin A, Dihydrobiochanin A, Phenylacetic acids, Fusarium javanicum 
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 TEI-XML for    default:Reihe_C/37/ZNC-1982-37c-0861.pdf 
 Identifier    ZNC-1982-37c-0861 
 Volume    37