| 1 | Author
| HerbertW. Roesky, Ulrich Seseke, Mathias Noltemeyer, GeorgeM. Sheldrick | Requires cookie* | | Title
| Darstellungen und Strukturen viergliedriger Metall-Stickstoff-Ringe Preparations and Structures of Four-Membered Metal-Nitrogen Rings  | | | Abstract
| Ph 3 P=NSiMe 3 (1) reacts with InCl 3 , SnCl, and FeCl, to yield (Ph,P=N) 2 (InCl 2) 2 • 2 DMF (2a), (Ph 3 P=N) 2 Sn 2 Cl 4 • 2 CH 3 CN (3a) and (Ph 3 P=N) 2 (FeCl 2) 2 (4). The X-ray single crystal structures of 2a, 3a and 4 are reported. The compounds form four-membered rings consisting of alternating metal and nitrogen atoms. 2a and 4 are symmetrical, but 3a has both a Sn(II)Cl and a Sn(IV)Cl 3 group in the four-membered ring. | | |
Reference
| Z. Naturforsch. 43b, 1130—1136 (1988); eingegangen am 29. März 1988 | | |
Published
| 1988 | | |
Keywords
| Indium, Tin, Iron, X-Ray | | |
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| default:Reihe_B/43/ZNB-1988-43b-1130.pdf | | | Identifier
| ZNB-1988-43b-1130 | | | Volume
| 43 | |
|