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'Iron Ruthenium Double Bond' in keywords
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1995 (1)
1Author    Hans-Christian Böttcher3-, Helmut Hartungb, Andre KrugbRequires cookie*
 Title    Synthese und Kristallstruktur des koordinativ ungesättigten Komplexes [FeRu(CO)5(//-P B u92] Synthesis and Crystal Structure of the Coordinatively Unsaturated Complex [FeR u(C O )5Cu-PBu92]  
 Abstract    [{Ru(CO)3C12}2] reacts with the in situ prepared reagent Li2[Fe(CO)3(PBu2)2] to give the new heterobinuclear complex [FeRu(CO)5(w-PBu92] (!) • Crystals of 1 are isomorphous to those of the known compound [Fe2(CO)5(a-PBu2)2] (2) and crystallize in the triclinic space group P 1 with a = 867,5(1), b = 1181,0(2), c = 1373,1(2) pm; a = 76,64(1), ß = 79,72(1) and y = 76,48(1)°. A double bond between the two metal atoms concluded for 2 from the results of EHMO calcula­ tions is also proposed for 1 (Fe=Ru: 259,8(1) pm). 
  Reference    Z. Naturforsch. 50b, 1175—1180 (1995); eingegangen am 19. Januar 1995 
  Published    1995 
  Keywords    Iron-Ruthenium Complex, H eterobinuclear Carbonyl Complex, Iron-Ruthenium Double Bond, Crystal Structure, Molecular Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1175.pdf 
 Identifier    ZNB-1995-50b-1175 
 Volume    50