| | 1 | Author
| Dieter Sellmann+, MarcusH. Annakam, Falk Knoch, M. Atthias, Moll | Requires cookie* | | | Title
| Übergangsmetallkomplexe mit Schwefelliganden, XCII*. Oxidation von Thiolat-Amin-zu Schiffbase-Eisen(II)  | | | | Abstract
| Komplexen. Röntgenstrukturanalyse und Reaktivität von [Fe('N2S2')]2 (N2S2'2" = Glyoxal-bis(2 -mercaptoanil)(2 -)) Transition M etal Complexes with Sulfur Ligands, XCII*. Oxidation o f Thiolate Amine to Schiff Base Iron(II) Complexes. X-Ray Structure Analysis and Reactivity of [Fe('N2S2')]2 ('N 2S2'2_ = Glyoxal-bis(2-mercaptoanil)(2-)) Oxidation o f [Fe(CO)2('N 2H2S2')] (1) ('N 2H2S2'2_ = l,2-ethanediam ine-N ,N '-bis(2-benzene-thiolate)(2—)) gave insoluble [Fe('N2S2')]2 (2) ('N2S2'2_ = glyoxal-bis(2-m ercaptoanil)(2-)). Dinuclear, thiolato-bridged 2 was characterized by single crystal X-ray structure analysis. It does not react with CO or H 2, but yields bis or mono adducts with PR 3 (R = M e, rc-Bu, Cy). | | | |
Reference
| Z. Naturforsch. 47b, 1545—1550 (1992); eingegangen am 17. April 1992 | | | |
Published
| 1992 | | | |
Keywords
| Thiolate Am ine, Iron(II) Complexes, Oxidation, X-Ray | | | |
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| ZNB-1992-47b-1545 | | | | Volume
| 47 | |
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