| | 1 | Author
| Dieter Sellm, Helge Friedrich, Falk Knoch | Requires cookie* | | | Title
| Synthese und Struktur von *1,33N2H4 Transition Metal Com plexes with Sulfur Ligands, Cl*. Synthesis and Structure of N 2H 5[Fe(N 2H4)(S2C6H4)2] * 1,33 N 2H 4  | | | | Abstract
| A ttem pts to coordinate N2H4 to [Fe(S2C6H 4)2] fragments lead to N2H 5[Fe(N2H 4)(S2C6H4)2], which crystallizes from M eOH/N2H 4 solutions as the solvate [(N2H 5){Fe(N2H4)(S2C6H4)2} T.33 N2H 4], 1, and has been characterized by X-ray structure analysis. 1 contains three discrete N2H 5+ cations, four N2H4 solvate molecules and three independent [Fe(N2H4)(S2C6H4)2] anions which are connected via an extended network of N -H —N and N -H —S bridges. N2H 5[Fe(N2H 4)(S2C6H4)2] and 1 contain high-spin Fe(III) centers and labile N2H4 ligands. Ubergangsmetallkomplexe mit Schwefelliganden, CI*. | | | |
Reference
| Z. Naturforsch. 49b, 660—664 (1994); eingegangen am 22. Dezember 1993 | | | |
Published
| 1994 | | | |
Keywords
| Iron Sulfur Hydrazine Complexes, Synthesis, X-Ray | | | |
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| default:Reihe_B/49/ZNB-1994-49b-0660.pdf | | | | Identifier
| ZNB-1994-49b-0660 | | | | Volume
| 49 | |
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