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1986 (1)
1Author    R. Ajib, Lai De, Heinrich VahrenkampRequires cookie*
 Title    Synthesen neuer Fe—P-Käfigverbindungen Syntheses of New Fe —P Cage Compounds  
 Abstract    Four reaction types were used with the aim of obtaining new cage com pounds o f com position F e v(C O)v(P R). with R = M e, Ph. Tol; oxidation of the com pounds Fe2(C O)A(P H R)2. photolysis thereof, reaction betw een RPC12 and Fe2(C O)x:_ , and reaction betw een P —Cl containing iron com plexes and F e(C O)42" . Besides several known products, e.g. F e,(C O)y(P R)2 or F e4(C O)M(P R)2, and derivatives of the Fe2(C O)ft(P R X)2 butterfly type com plexes, the new octabisvalene shaped com pounds Fe4(C O)I2(P R)4 with R = M e. Ph. Tol were obtained and confirm ed by a crystal structure analysis for R = Me. Side products of the oxidative conversions were Fe4(C O),2(P 2M e2) (M e P -C 2H 4-P M e) and Fe4(C O)12(P2T ol2)(P H T ol)2 which can be derived from the octabisvalene type. Side products o f the irradiative conversions were F e,(C O)s(P P h)(P H P h)2 and (C O),F e(a-P H P h)2F e(C O)(Q ,H 8), the structure o f the latter being proved crystallographically. 
  Reference    Z. Naturforsch. 41b, 273 (1986); eingegangen am 23. O ktober 1985 
  Published    1986 
  Keywords    Iron Phosphorus Cage Com pounds, Synthesis, Structure 
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 TEI-XML for    default:Reihe_B/41/ZNB-1986-41b-0273.pdf 
 Identifier    ZNB-1986-41b-0273 
 Volume    41