| | 1 | Author
| Roland Boese, Dieter Bläser, Wolfgang Petz | Requires cookie* | | | Title
| [Fe(C0)  | | | | Abstract
| 4 C(0)NMe 2 ][C(NMe 2)3]; die erste Strukturbestimmung einer Organometallverbindung mit dem Carbeniumion [C(NMe 2) 3 ] + [Fe(C0) 4 C(0)NMe 2 ][C(NMe 2) 3 ]; the First Structure Determination on an Organometallic Compound with the Carbenium Ion [C(NMe 2) 3 ] + The crystal structure of the carbamoyl complex [(C0) 4 FeC(0)NMe 2 ][C(NMe 2) 3 ] (1) is de-scribed. It crystallizes in the triclinic space group PI (a = 7.876(3), b = 10.098(3), c = 12.067(5)Ä, a = 94.25(3), ß = 90.94(3), y = 97.30(3)°, Z = 2) and consists of independent ions. The cation has a planar CN 3 array with sp 2 hybridized C and N atoms. The carbamoyl group of the anion occupies an axial position in the trigonal bipyramidal environment of the iron atom. | | | |
Reference
| Z. Naturforsch. 43b, 945—948 (1988); eingegangen am 26. Februar/14. April 1988 | | | |
Published
| 1988 | | | |
Keywords
| Crystal Structure, Iron Complex, Carbamoyl Complex, Guanidinium Cation | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0945.pdf | | | | Identifier
| ZNB-1988-43b-0945 | | | | Volume
| 43 | |
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