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'Iron Complex' in keywords Facet   Publication Year 1982  [X]
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1982[X]
1Author    Udo Kunze, Antonios AntoniadisRequires cookie*
 Title    Phosphinsubstituierte Chelatliganden, IV [1] Neue Diphenylphosphinoformamid-Komplexe des Mangans und Eisens Phosphine Substituted Chelate Ligands, IV [1] New Diphenylphosphino Formamide Complexes of Manganese and Iron  
 Abstract    The phosphino and (thio)phosphoryl formamides la, b, 2a-c, 3a, b, 4a, b which were partially unknown are synthesized by various methods, and their reactions with carbonyl-metal halides of manganese and iron are described. The formation of the P,N-and S,N-coordinate chelate complexes, (CO)4MnL (5 a, 8a), is limited to the N-phenyl derivatives la and 4a. With L = 2a, b, the unidentate P-coordination predominates. Thus, the carbonylmetal halide complexes cis-(CO)4Mn(X)L (6a, b: X = CI, 7a, b: X = Br) and 7? 5 -C5H5(CO)Fe(X)L (9a, b: X = I, 10a, b: X = Br) are obtained. Due to the low stability of the formamide complexes, their formation is always accompanied by isocyanate elimi-nation as a side-reaction. 
  Reference    Z. Naturforsch. 37b, 560—567 (1982); eingegangen am 17. November 1981 
  Published    1982 
  Keywords    Chelate Ligands, Phosphino Formamide, Manganese Complexes, Iron Complexes, Isocyanate Elimination 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0560.pdf 
 Identifier    ZNB-1982-37b-0560 
 Volume    37