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1981 (1)
1Author    H. Kisch, C. Krüger, A. TrautweinRequires cookie*
 Title    Übergangsmetallkomplexe von Diazenen, XVI [1] Struktur und Mößbauerdaten von (2.3-Diazanorbornen)Fe3(CO)9 Transition Metal Complexes of Diazenes, XVI [1] Structure and Mössbauer Data of (2,3-Diazanorbornene)Fe3(CO)g  
 Abstract    The molecular structure of (2,3-diazanorbornene)Fe3(CO)9 consists of a triangular Fe3(CO)g group bound to the diazene unit. The seven-coordinated Fe(CO)3 group forms two Fe-N bonds with lengths of 1.974 and 1.965 Ä, each of the two six-coordinated Fe(CO)3 groups has slightly shorter Fe-N-bonds of 1.898 and 1.903 Ä. One Fe-Fe distance, 2.612Ä, is longer than the two other ones, 2.572 and 2.582 A, which are in the range of typical single bonds. The presence of seven-and six-coordinated iron carbonyl groups is also demonstrated by the Mössbauer spectrum showing signals with quadrupole splittings of 1.23 and 0.78, 0.62 ± 0.01 mm/s, respectively. 
  Reference    Z. Naturforsch. 36b, 205—207 (1981); eingegangen am 2. Dezember 1980 
  Published    1981 
  Keywords    Diazenes, Iron Cluster, X-ray, Mössbauer Data 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0205.pdf 
 Identifier    ZNB-1981-36b-0205 
 Volume    36