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'Iridium' in keywords Facet   section ZfN Section B  [X]
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1Author    Ernst Guggolz, ManfredL. Ziegler, Willibald Kalcher, Johann Plank, Doris Riedel, WolfgangA. HerrmannRequires cookie*
 Title    Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (^-C5Me5)IrFea(CO)9 Synthesis and Molecular Structure of the Trinuclear Cluster Compound (^ 5 -C5Me5)IrFe2(CO)g  
 Abstract    Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(?? 5 -C5Me5)Ir(//-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (rj 5 -C&Mes)IrFe2(C0)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (j7 5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8. 
  Reference    Z. Naturforsch. 36b, 1053—1059 (1981); eingegangen am 8. April 1981 
  Published    1981 
  Keywords    Iron, Iridium, Carbonyl Complexes, Pentamethylcyclopentadienyl 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1053.pdf 
 Identifier    ZNB-1981-36b-1053 
 Volume    36 
2Author    Thomas Pill, Wolfgang BeckRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, LXVI [1). Rhodium(III)-, Iridium(III)-, Palladium(II)-, Platin(II)-und Gold(I)-Komplexe von N-(2,3,4,6-Tetra-0-acetyl-/?-D-glucopyranosyl)-thiocarbamatestern und /?-D-Glucopyranosylthioharnstoff Metal Complexes o f Biologically Im portant Ligands, LXVI [1], Rhodium(III), Iridium (III), Palladium(II), Platinum (II), Gold(I) Complexes of N-(2,3,4,6-Tetra-0-acetyl-/?-D-glucopyranosyl)-thiocarbamate Esters and /?-D-Glucopyranosylthiourea  
 Abstract    From N-(2,3,4,6-tetra-0-acetyl-/?-D-glucopyranosyl)-thiocarbamate esters (L 1) the complexes (75-C5M e5)(Cl2)M (L') (M = Rh, Ir), C l(M e,N C H 7C6H4)Pd(LI), trans-(«-Bu3P)(Cl)2M (L') (M = Pd, Pt), /ra«5-Cl2P t(L 1)2, [(Ph3P)2(C l)Pt(L')]+, Cl2Pt(//-L')PtCl2 and C lA uL1 have been obtained. /?-D-glucopyranosylthiourea (L2) forms the complexes (>75-C5M e5)(Cl)-,M(L2) (M = Rh, Ir), (C l)M e2N C H 2C6H 4)Pd(L2), (Et3P)Cl,Pd(L2) and C12M (L2)2 (M = Pd, Pt). 
  Reference    Z. Naturforsch. 48b, 1461—1469 (1993); eingegangen am 27. April 1993 
  Published    1993 
  Keywords    Rhodium, Iridium, Palladium, Platinum, G old 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1461.pdf 
 Identifier    ZNB-1993-48b-1461 
 Volume    48 
3Author    Kay Severin, Wolfgang BeckRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, LXXVII [1] Synthese und Reaktionen von Dihydrido-Iridium(III)-Komplexen mit a-Aminocarboxylat-Liganden Metal Complexes of Biologically Im portant Ligands, LXXVII [1] Synthesis and Reactions of Dihydrido-Iridium (III) Complexes of a-A m ino Carboxylates  
 Abstract    Dihydrido-iridium(III) complexes of the general formula IrH2(aa)(PPh3)2 (aa = L-ala-ninate, L-valinate, L-prolinate and L-phenylalaninate, 1 -4) have been synthesized. Reac­ tions of 1 -3 with phenylacetylene give the hydrido-di(phenylethynyl) complex IrH(C=CPh)2(PPh3)3 (5). The latter compound is also formed from IrH3(PPh3)3 and phenyl­ acetylene. All complexes have been characterized by NMR ('H, 13C, 31P) and IR spectro­ scopy. 
  Reference    Z. Naturforsch. 50b, 275—279 (1995); eingegangen am 10. Oktober 1994 
  Published    1995 
  Keywords    Iridium, a-Amino Acids, Dihydrido Complexes, Phenylethynyl Complex 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0275.pdf 
 Identifier    ZNB-1995-50b-0275 
 Volume    50 
4Author    Lutz Dahlenburg, Fazlollah Mirzaei, Ah YardimciogluRequires cookie*
 Title    Alkyl-und Arylkomplexe des Iridiums und Rhodiums  
 Abstract    , IX [1] Organorhodiumverbindungen Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) und homologe Iridiumalkyle Alkyl and Aryl Complexes of Iridium and Rhodium, IX [1] Organorhodium Compounds Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) and Related Iridium Alkyls A series of organorhodium and -iridium complexes M(R)(CO)(PPh 3)2 (M = Rh: R = CeHs, 2-MeC6H4, 4-MeC6H4, 2,4,6-Me3C6H2, CH3, CH2SiMe3, CH2CMe3; M = Ir: R = CH3, CH2Ph, CH2SiMe3, CH2CMe3) has been prepared from MCl(CO)(PPh3)2 and the correspond-ing organolithium or Grignard reagents. Of these compounds, the mesitylrhodium complex Rh(2,4,6-Me3C6H2)(CO)(PPh3)2 as well as the iridium and rhodium alkyls with Me3SiCH2 and Me3CCH2 ligands show cis,irans-isomerism which is demonstrated on the basis of infrared and NMR spectroscopic evidence. 
  Reference    Z. Naturforsch. 37b, 310—317 (1982); eingegangen am 23. Oktober 1981 
  Published    1982 
  Keywords    Rhodium, Iridium, Organometallic Compounds, eis, frarw-Isomerism, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0310.pdf 
 Identifier    ZNB-1982-37b-0310 
 Volume    37 
5Author    Rostislav Lam, ShahramM. Ihanb, Wolfgang BeckbRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, LXXXY [1] Koordinationsverbindungen von Cobalt(III), Iridium(III), Ruthenium(II) und Palladium(II) mit Isoxazol-und Isoxazolin-3-carboxylaten M etal Complexes of Biologically Im portant Ligands, LXXXV [1] Coordination Compounds of C obalt(III), Iridium (III), R uthenium (II) and Palladium(II) with Isoxazole-and Isoxazoline-3-carboxylates  
 Abstract    Chelate complexes of 5-phenyl-isoxazole-3-carboxylate (L 1) and 5-phenyl-isoxazoline-3-carboxylate (L2) ligands were prepared: PdfL 1)-). C p*(C l)Ir(L '), (p-cym ene)(Cl)Ru(L1), Pd(L2)2, (Et3P)(Cl)Pd(L2), C6H4CH 2N M e2Pd(L2)-L 2H, Cp*(I)Co(L2), Cp*(Cl)Ir(L2) (10), and (p-cymene)(Cl)Ru(L2) (Cp* = C5Me5). The structure of 10 was determined by X-ray diffraction. 
  Reference    Z. Naturforsch. 51b, 581—587 (1996); eingegangen am 27. Juli 1995 
  Published    1996 
  Keywords    Isoxazole-3-carboxylate, Isoxazoline-3-carboxylate, Chelate Complexes, Cobalt, Iridium 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0581.pdf 
 Identifier    ZNB-1996-51b-0581 
 Volume    51