| | 1 | Author
| Lutz Dahlenburg, Fazlollah Mirzaei, Ah Yardimcioglu | Requires cookie* | | | Title
| Alkyl-und Arylkomplexe des Iridiums und Rhodiums  | | | | Abstract
| , IX [1] Organorhodiumverbindungen Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) und homologe Iridiumalkyle Alkyl and Aryl Complexes of Iridium and Rhodium, IX [1] Organorhodium Compounds Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) and Related Iridium Alkyls A series of organorhodium and -iridium complexes M(R)(CO)(PPh 3)2 (M = Rh: R = CeHs, 2-MeC6H4, 4-MeC6H4, 2,4,6-Me3C6H2, CH3, CH2SiMe3, CH2CMe3; M = Ir: R = CH3, CH2Ph, CH2SiMe3, CH2CMe3) has been prepared from MCl(CO)(PPh3)2 and the correspond-ing organolithium or Grignard reagents. Of these compounds, the mesitylrhodium complex Rh(2,4,6-Me3C6H2)(CO)(PPh3)2 as well as the iridium and rhodium alkyls with Me3SiCH2 and Me3CCH2 ligands show cis,irans-isomerism which is demonstrated on the basis of infrared and NMR spectroscopic evidence. | | | |
Reference
| Z. Naturforsch. 37b, 310—317 (1982); eingegangen am 23. Oktober 1981 | | | |
Published
| 1982 | | | |
Keywords
| Rhodium, Iridium, Organometallic Compounds, eis, frarw-Isomerism, NMR Spectra | | | |
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| default:Reihe_B/37/ZNB-1982-37b-0310.pdf | | | | Identifier
| ZNB-1982-37b-0310 | | | | Volume
| 37 | |
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