| | 1 | Author
| Wilhelm Klein3, Martin Jansenb | Requires cookie* | | | Title
| Darstellung und Kristallstruktur von Lithiumozonid-Ammoniakat (1/5) Li(> 3 * 5 NH3 Synthesis and Crystal Structure of Lithiumozonide-Ammonia (1/5) L i0 3 * 5 NH3  | | | | Abstract
| Lithium ozonide has been synthezised starting from cesium ozonide via cation exchange in liquid ammonia and crystallizes at -78°C as an ammoniate, L i0 3 • 5NH3. The coarse, ruby red crystals decompose above the boiling temperature of ammonia and are extremely sensitive to moisture. The crystal structure of L i0 3 • 5NH3 (P c2\n; a = 1231.9(5), b = 637.4(2), c = 1104.8(4) pm; Z = 4; /?, = 4.57%; 1318 independent reflections) consists of lithium tetramine complexes, ozonide anions and non coordinating ammonia molecules. With respect to the arrangement of the complex cations and of the anions there is similarity to the WC type of structure. The central oxygen atom of the ozonide anion is disordered. | | | |
Reference
| Z. Naturforsch. 54b, 1345—1349 (1999); eingegangen am 28. Juni 1999 | | | |
Published
| 1999 | | | |
Keywords
| Lithium Ozonide Ammonia, Ionic Ozonides, Lithium Tetramine Complex, Crystal Structure | | | |
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| default:Reihe_B/54/ZNB-1999-54b-1345.pdf | | | | Identifier
| ZNB-1999-54b-1345 | | | | Volume
| 54 | |
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