| | 1 | Author
| Hans Hartl, Irene Brüdgam | Requires cookie* | | | Title
| Synthese und Strukturuntersuchungen von Iodocupraten(I)  | | | | Abstract
| X . [Co(cp)2]2[CuI3] und [Co(cp)2][Cu2I3] = l/9{[Co(cp)2]9[Cu6Iu Ji [(Cn6I8)2]} [ 1 ] Syntheses and Structure Analyses of Iodocuprates(I) X. [Co(cp)2]2[CuI3] and [Co(cp)2][Cu2I3] = l/9{[Co(cp)2]9[Cu6I n]2[(Cu6I8)2]} [1] Bis-(cobalticenium)triiodocuprate(I), [ C o (c p) 2]2[ C u I , ] s (l) and cobalticenium-triiodo-dicuprate(I), [Co(cp)2][Cu2I,]=l/9{[Co(cp)2]9[Cu6I u ] 2 [(Cu6I8)2]}==(2) were obtained by reacting [Co(cp)2]I with Cul in acetone 1 and acetonitrile 2, respectively. The crystal structure of 1 exists of cobalticenium cations and mononuclear planar anions C u l,2". The crystal structure of 2 contains cobalticenium cations and two different types of iodocuprate(I) anions: an isolated hexa-nuclear ion Cu6I n5-built up by 6 edge sharing C ul4 tetrahedra and polymeric layers 2 [CuftI8]2-. In the latter anion Cu6I n components are two-dimensionally connected via 3 common edges and Cu(I) ions are distributed over two kinds of tetrahedral sites. | | | |
Reference
| Z. Naturforsch. 44b, 936—941 (1989); eingegangen am 10. März/28. April 1989 | | | |
Published
| 1989 | | | |
Keywords
| Iodocuprate(I), Cobalticenium Cation, Crystal Structure, Synthesis | | | |
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| default:Reihe_B/44/ZNB-1989-44b-0936.pdf | | | | Identifier
| ZNB-1989-44b-0936 | | | | Volume
| 44 | |
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