1 | Author | Siegfried Pohl, Michael Peters, Detlev Haase, Wolfgang Saak | Requires cookie* |
Title | Bildung von Iodoantimonaten und -bismutaten. Kristallstrukturen von (PhCH2NEt3)4 [Sb6l 2 2 L (PhCH2NEt3)4 [Bi6l 2 2 ] und (Ph4P)3[Bi5I18] Form ation of Iodoantim onates and Bismutates. Crystal Structures of (PhCH 2N E t3)4[Sb6I22], (PhC H 2N Et3)4[Bi6l22] and (Ph4P)3[Bi5I 18] ![]() | ||
Abstract | The formation and the crystal structures of the title compounds are reported. (PhCH2N E t3)4[Sb6l 22] and (PhCH 2N E t3)4[Bi6l 22] are isotypic and contain a novel [E6I22]4~ anion (E = Sb, Bi). The anion of (Ph4P)3[Bi5I18] consists of a linear chain of five face-sharing [B il6] octahedra. | ||
Reference | Z. Naturforsch. 49b, 741—7 (1994); eingegangen am 27. Januar 1994 | ||
Published | 1994 | ||
Keywords | Iodoantimonates, Iodobismutates, Crystal Structure | ||
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