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'Iodoantimonates' in keywords Facet   Publication Year 1988  [X]
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1988[X]
1Author    Siegfried Pohl, Rainer Lötz, Detlev Haase, Wolfgang SaakRequires cookie*
 Title    Iodoantimonate der Zusammensetzung A + Sb 2 I 7 : Diskrete Anionen in (Me 4 N) 4 Sb 8 I 2 8 und (Me 3 S) 4 Sb 8 I 28 , polymere Ketten in (Me 3 NCH 2 Ph)Sb 2 I 7 (Me = CH 3 , Ph = C 6 H 5 ) Iodoantimonates of Composition A~Sb 2 I 7 ~: Discrete Anions in (Me 4 N) 4 Sb 8 I 28 and (Me 3 S) 4 Sb s I 28 , Polymerie Chains in (Me 3 NCH 2 Ph)Sb 2 I 7 (Me = CH 3 , Ph -C 6 H 5 )  
 Abstract    The reaction of Sbl 3 with Me 4 NI, Me ? SI, and Me^NCH^Phl in acetonitrile (molar ratios 2:1) yields (Me 4 N) 4 Sb 8 I 28 (1). (Me,S) 4 Sb K I 28 (2). and (Me,NCH 2 Ph)Sb : I 7 (3), respectively. The struc-tures of 1—3 were determined from single crystal X-ray diffraction data. 1—3 crystallize in the monoclinic space group P2,/«. 2: a -1434.2(3). b -1484.1(4). c = 2102.6(4) pm. ß = 105.4(1)°, Z = 2. 1: a = 1441.7(1), b = 1545.1(1). c = 2117.3(1) pm. ß = 106.4(1)°, Z = 2. 3: a = 1004.4(1). b = 1378.8(1). c = 1899.3(2) pm. ß = 94.2(1)°. Z = 4. The structures of 1 and 2 are very similar and consist of isolated cations and anions. The Sb s I 28 
  Reference    Z. Naturforsch. 43b, 1144—1150 (1988); eingegangen am 24. Mai 1988 
  Published    1988 
  Keywords    Iodoantimonates, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1144.pdf 
 Identifier    ZNB-1988-43b-1144 
 Volume    43