| | 1 | Author
| Klaus Angerm, Borislav Bogdanović, GudrunK. Oppetsch, Carl Krüger, RichardM. Ynott, Manfred Schwickardi, Yi-H Ung Tsay | Requires cookie* | | | Title
| Magnesiumorganische Innerkomplexe, Teil I [1] Bis(dialkylaminoalkyl)-und Bis(alkoxybutyl)magnesium-Verbindungen Organomagnesium Inner C om plexes, Part I [1] Bis(dialkylaminoalkyl)-and Bis(alkoxybutyl)m agnesium Compounds  | | | | Abstract
| A series of magnesium inner complexes has been prepared by reacting M gH2 (prepared by homogeneous catalysis) with dialkylallyl-and -3-butenylam ines and -3-butenylethers in the p re sence of catalytic amounts of Z rC l4. The m onom eric nature of bis(4-m ethoxybutyl)m agnesium has been confirmed by X-ray diffraction. The analogous syntheses of bis(3-alkoxypropyl)magnesium com pounds failed: cleavage of the allyl ether with elimination of propene occurred. This cleavage reaction is accelerated by catalytic amounts of NiCl2 or ZrC l4. | | | |
Reference
| Z. Naturforsch. 41b, 455 (1986); eingegangen am 21. N ovem ber 1985 | | | |
Published
| 1986 | | | |
Keywords
| Magnesium, Inner Complexes, Crystal Structure, X-Ray | | | |
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| default:Reihe_B/41/ZNB-1986-41b-0455.pdf | | | | Identifier
| ZNB-1986-41b-0455 | | | | Volume
| 41 | |
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