| | 1 | Author
| JohnL. Huppatz, JohnN. Phillips | Requires cookie* | | | Title
| Cyanoacrylate Inhibitors of the Hill Reaction III. Stereochemical and Electronic Aspects of Inhibitor Binding  | | | | Abstract
| Ethoxyethyl 3-octylamino-2-cyanoacrylate and related com pounds in which the am ino group was replaced by N -C H 3, S, O and CH 2 were synthesized and their activity as inhibitors o f the Hill reaction in isolated pea chloroplasts determ ined. All com pounds show ed m oderate to high activity but there was no obvious correlation between activity and the electronic character o f the ester carbonyl group. The stereochemistry o f the various inhibitor m olecules was deduced from the PMR spectra and the possible influence o f stereochem istry on Hill inhibitory activity discussed. Replacement o f the olefinic proton in the 2-cyanoacrylates with a /?-alkyl substituent was examined and a specific relationship between the length o f the alkyl chain and activity was observed. | | | |
Reference
| Z. Naturforsch. 39c, 617 (1984); received D ecem ber 28 1983 | | | |
Published
| 1984 | | | |
Keywords
| Cyanoacrylates, Inhibitors o f Electron Transport, Hill Reaction, Stereochemistry | | | |
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| default:Reihe_C/39/ZNC-1984-39c-0617.pdf | | | | Identifier
| ZNC-1984-39c-0617 | | | | Volume
| 39 | |
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