| 1 | Author | Z. Naturforsch | Requires cookie* |
| Title | Indium Triiodide Complexes of Bis(diphenyIphosphino)ethane (dppe) and its Disulfide (dppeS2)  | ||
| Abstract | Bis(diphenylphosphino)ethane (dppe) and its disulfide (dppeS2) react with two equivalents of indium triiodide to give high yields of the corresponding 1:2 adducts. According to crys tal structure determinations, both compounds are molecular bis-terminal complexes with the ligands in an all-trans conformation. Contrary to previous findings for complexes of the indium trihalides and of G aB r3 and G al3 with ditertiary phosphines in fixed cis-structure [bis(diphenylphosphino)ethene or -benzene], no iodide redistribution is observed to give the ionic species [(dppe)Inl2]+ [InL ]-. The molecular structures are also retained in solution. | ||
| Reference | (Z. Naturforsch. 54b, 21—25 [1999]; received October 10 1998) | ||
| Published | 1999 | ||
| Keywords | Indium Triiodide, Phosphine Complexes, Phosphine Sulfide Complexes, Conformation, Crystal Structure | ||
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