| | 1 | Author
| Thomas Kräuter, Bert Werner, Bernhard Neumüller | Requires cookie* | | | Title
| Synthese  | | | | Abstract
| und Eigenschaften von Benzylgallium(indium)-Verbindungen. Die Kristallstrukturen von [(PhCH2)2GaBr]2, [(PhCH2)2GaN(H)f-Bu]2 und [PhCH2InCl2(THF)2] Synthesis and Properties o f Benzylgallium(indium) Compounds. The Crystal Structures o f [(PhCH2)2GaBr]2, [(PhCH2)2GaN(H)r-Bu]2 and [PhCH2InCl2(THF)2] (PhCH2)2GaBr (1) can be obtained by the redistribution reaction of GaBr3 with Ga(CH2Ph)3 in a molar ratio 1:2. Treatment of 1 or (PhCH2)2GaCl with one equivalent of LiN(H)/-Bu gives the diorganogallium amide [(PhCH2)2GaN(H)r-Bu]2 (2). The toluene-insoluble PhCH2InCl2 can be structurally investigated after dissolving in THF and crystallization as [PhCH2InCl2(THF)2] (3). 1 -3 were characterized with NMR, IR and MS techniques as well as by X-ray structure determinations. 1 forms two crystallographic independent dimers while 2 is a centrosymmetric dimer in the solid state. 3 is a monomer with a trigonal-bipyramidal coordination sphere at the indium center. | | | |
Reference
| Z. Naturforsch. 51b, 637—645 (1996); eingegangen am 14. September 1995 | | | |
Published
| 1996 | | | |
Keywords
| Gallium Compounds, Indium Compound, Crystal Structure | | | |
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| default:Reihe_B/51/ZNB-1996-51b-0637.pdf | | | | Identifier
| ZNB-1996-51b-0637 | | | | Volume
| 51 | |
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