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2000 (1)
1Author    Jürgen Schatz3, Frank Schildbacha, AxelL.Requires cookie*
 Title    The Inclusion of Carbon Disulfide in /?-rerf-Butylcalix[4]-and [6 ]arene - A Combined Crystallographic and Vibrational Spectroscopic Study  
 Abstract    en tzb, Sylvia R a stä tte rb, Joachim Schilling5, Jö rg D o rm an n c, A n d reas R uoffc, and Tony D eb ae rd em ae k erd The inclusion complexes formed from carbon disulfide and /?-r£7-r-butylcalix[4]arene (1 C S 2) or /?-rm-butylcalix[6]arene (2-C S2) were investigated by X-ray crystal structure analysis, infrared (IR) and Raman spectroscopy. The complex 1 C S 2 crystallises in the space group P4/n, 2 C S 2 in the space group P2xln. In case of /?-rm-butylcalix[4]arene as host the carbon disulfide molecule is included in the cavity. In the crystal structure of p-rm -butylcali-x[6]arene clathrate, self-com plexation o f one rm-butyl group in the cavity o f another ca-lix[6]arene can be observed. Due to inclusion, the symmetry of CS2 is lowered both in the p-rm -butylcalix[4]arene and p-rm-butylcalix[6]arene case causing significant shifts in the fully assigned infrared and Raman spectra. 
  Reference    Z. Naturforsch. 55b, 213—221 (2000); received N ovem ber 16. 1999 
  Published    2000 
  Keywords    p-rerz-Butylcalixarenes, Inclusion Complexes, Crystal Structure, IR Data, Raman Data 
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 TEI-XML for    default:Reihe_B/55/ZNB-2000-55b-0213.pdf 
 Identifier    ZNB-2000-55b-0213 
 Volume    55