| | 1 | Author
| Kurt Merzweiler, D. Ieter Fenske, Eva Hartm, Ann, Kurt Dehnicke | Requires cookie* | | | Title
| Synthese und Kristallstruktur des Imidokomplexes {TaCl4NC(Ph)[N(SiM e3)2]}2 * 2 C H 2C 12 Synthesis and Crystal Structure of the Imido Complex {TaCl4NC(Ph)[N(SiM e3)2]}2 * 2 C H 2C12  | | | | Abstract
| The title com pound has been prepared by the reaction of N ,N,N '-tris(trim ethylsilyl)benz-amidine with tantalum pentachloride in C H 2CL suspension, forming am ber-coloured, moisture-sensitive crystals, which were characterized by an X-ray structure determ ination. Space group P 2,In, Z = 2, 4895 observed independent reflexions, R = 0.059. Lattice dimensions (— 65 °C): a — 1165.2(6), b -1335.4(6), c = 1629.0(7) pm, ß -93.23(4)°. The complex forms centrosymmetric molecules dimerized via chloro bridges TaCLTa with TaCl bond lengths of 247.2(2) and 277.1(2) pm, the longer one being in frarcs-position to the imido group, which can be formulated a sT * a= $ = C < *M (bond len g th sT a= N = 183.5(8), C = N = 134(1) pm. bond angle TaNC = Ph 162.7(7)°). | | | |
Reference
| Z. Naturforsch. 44b, 1003 (1989); eingegangen am 8. Mai 1989 | | | |
Published
| 1989 | | | |
Keywords
| Imido Complex of Tantalum, Synthesis, IR Spectra, Crystal Structure | | | |
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| default:Reihe_B/44/ZNB-1989-44b-1003.pdf | | | | Identifier
| ZNB-1989-44b-1003 | | | | Volume
| 44 | |
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