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'IV Compound' in keywords Facet   Publication Year 1984  [X]
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1Author    Mario Cannas, Giaime Marongiu, HeimoJ. Keller, Barbara Müller, Reinhold MartinRequires cookie*
 Title    Structure of the Linear-Chain Mixed Valence Compound Bis(l,3-diaminopropane)platinum(II)bis(l,3-diaminopropane)- diiodoplatinum(IV)tetraperchlorate  
 Abstract    The title compound CpH49Cl4LN80 16Pt-,, Mr 1314.1, is monoclinic P 2, (from structural analy­ sis), a = 8.74(1), b = 11.36(1), c = 8.63(1), ß = 107.6(5), V = 817 Ä 3, Z = 1, D m (flotation) = 2.65 g cm-3, D c = 2.66 g cm-3, MoKa A = 0.71069, /u = 110.7 cm-1, R = 0.063 for 1068 observed reflections. Rotation photographs show diffuse patterns corresponding to odd values of k together with weak Bragg reflections. Refinement of diffractometer data was carried out in space groups Pm, P2,/m and P2,; both refinement in Pm and P2, give satisfactory agreement and lead to very similar crystal structures. 
  Reference    Z. Naturforsch. 39b, 197 (1984); eingegangen am 5. September 1983 
  Published    1984 
  Keywords    Linear Chain, Mixed-Valence Platinum(II, IV) Compound 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0197.pdf 
 Identifier    ZNB-1984-39b-0197 
 Volume    39