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41Author    Glycine, GlycineEthyl Ester, Glycylglycine Ethyl, ]. Jurij, Ja Kharitonov, Herbert Bissinger, Eberhard Ambach, Wolfgang BeckRequires cookie*
 Title    IR-Spektren von Platin(II)-Komplexen mit Glycin, Glycin-und Glycylglycinethylester [1] IR-Spectra of Platinum(ll) Complexes with  
 Abstract    The infrared spectra (200-4000 cur 1) of trans-and cw?-Pt(NX2CH2COO)2 (X = H, D), trans-and cis-PtCl2(NH2CH2COOH)2, *rans-PtCl2(NH2CH2C02Et)2, cw-PtCl2(NX2CH2C02Et)2, cw-PtCl2(NX2CH2NXCH2C02Et)2 (X = H, D) and cis-PtY2(NH2CH2NHCH2C02Et)2 (Y = Br, I) including 15 N derivatives have been studied. There is no appreciable change of vibrat ional frequencies for corresponding eis-and trans-complexes which could be attributed to the irans-influence of different ligands. Due to lower symmetry most of the absorptions of the cis-complexes are split into doublets compared with the £rans-compounds. 
  Reference    Z. Naturforsch. 37b, 1034—1040 (1982); eingegangen am 22. März 1982 
  Published    1982 
  Keywords    IR Spectra, Glycine, Glycine Ester Platinum(II) Complexes 
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 Identifier    ZNB-1982-37b-1034 
 Volume    37 
42Author    Rolf Minkwitz, Rüdiger NaßRequires cookie*
 Title    Spektroskopische Untersuchungen an Monofluorammoniumsalzen Spectroscopic Studies on Monofluorammonium Salts  
 Abstract    The NMR, IR and Raman spectra of several NHaF+X -salts are reported. The prepara-tion of NH3F+SO3CI-and NH3F+SO3F-is described. 
  Reference    Z. Naturforsch. 37b, 1558—1563 (1982); eingegangen am 21. Juli 1982 
  Published    1982 
  Keywords    NMR Spectra, Raman Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1558.pdf 
 Identifier    ZNB-1982-37b-1558 
 Volume    37 
43Author    KarlE. Schwarzhans, Herwig SchottenbergerRequires cookie*
 Title    Ferrocenylen-cobaltocenylenium  
 Abstract    hexafluorophosphat [(h 5 :h 5 '-C10H8)2FeCo] [PF6], ein gemischtkerniger Komplex vom Bis(fulvalen)dimetall-Typus Ferrocenylenecobaltocenyleniumhexafluorophosphate [(h 5 : h 5 '-CioH8)2FeCo][PF6], Ferrocenylenecobaltocenylenium-monochloride and ferrocenylenecobaltocenylenium-hexafluorophosphate were prepared under the aspect of influencing the valence averaging phenomena described for homodinuclear metallofulvalenes. Detected paramagnetism of the monocation is assumed to result from such interactions in dibridged rigid metallocenes. The above cation is characterized by IR, CV, MS, electron microprobe and elemental analyses. 
  Reference    Z. Naturforsch. 38b, 1493—1496 (1983); eingegangen am 28. Juni 1983 
  Published    1983 
  Keywords    Ferrocenylenecobaltocenylenium-monochloride, IR Spectra, MS Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-1493.pdf 
 Identifier    ZNB-1983-38b-1493 
 Volume    38 
44Author    Paul Klingelhöfer, Ulrich Müller, HansG. Ünter Hauck, Kurt DehnickeRequires cookie*
 Title    ReCl5 * OPCl3; IR-Spektrum und Kristallstruktur ReCl5 -O PCl3; IR Spectrum and Crystal Structure  
 Abstract    Single crystals of ReCl5 • OPCl3 were obtained by cooling a saturated solution of rheniumpen­ tachloride in phosphorylchloride. It formes black needles, which are extremely sensitive to mois­ ture. In the IR spectrum v(PO) is shifted downwards by 140 cm-1 in comparison with liquid POCl3, indicating coordination via oxygen. The crystal structure was solved and refined from X-ray diffraction data (space group Pnma, four formula units per unit cell, a = 1629, b = 790, c = 877 pm, 902 observed, independent reflexions, R = 0.040). The complex forms discrete molecules ReCl5 • OPC1, with symmetry Cs (m). Bond lengths are Re —O — 214 pm and P —O = 146 pm, the angle Re —O —P is 143°. 
  Reference    Z. Naturforsch. 39b, 135 (1984); eingegangen am 8. September 1983 
  Published    1984 
  Keywords    Preparation, IR Spectra, X-Ray, Rheniumpentachloride Phosphorylchloride Adduct 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0135.pdf 
 Identifier    ZNB-1984-39b-0135 
 Volume    39 
45Author    RainerW. Eber, Kurt DehnickeRequires cookie*
 Title    Nitrosyl-und Thionitrosylkomplexe des Osmiums: [Os(NO)C15]9 und [Os(NS)CI5]G Nitrosyl-and Thionitrosyl Complexes of Osmium: [O s(N O )Cl5]e and [Os(NS)C15]q  
 Abstract    Osmium pentachloride reacts with NO forming the com plex N O [O s(N O)C l5], which when treated with (PPh3M e)C l yields PPh3M e[O s(N O)C l5] and nitrosyl chloride. The thionitrosyl com plex A sP h 4[O s(N S)C l5] is prepared by the reaction of 
  Reference    Z. Naturforsch. 39b, 262 (1984); eingegangen am 7. O ktober 1983 
  Published    1984 
  Keywords    Peptachloronitrosyl-osm ate, Pentachlorothionitrosyl-osm ate, Preparation, IR Spectra 
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 Identifier    ZNB-1984-39b-0262_n 
 Volume    39 
46Author    HelgeW. IllnerRequires cookie*
 Title    Das Infrarotspektrum von matrixisoliertem SFC1 Infrared Spectrum of M atrix Isolated SFCl  
  Reference    Z. Naturforsch. 39b, 314 (1984); eingegangen am 27. September/29. November 1983 
  Published    1984 
  Keywords    Sulfur Chloride Fluoride, IR Spectra, Force Constants 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0314.pdf 
 Identifier    ZNB-1984-39b-0314 
 Volume    39 
47Author    Ulrich Kynast, Elke Conradi, UlrichM. Üller, Kurt DehnickeRequires cookie*
 Title    Cyclo-thiazenokomplexe von Molybdän und Wolfram. Die Kristallstruktur von AsPh4[WCl4(N3S2)] Cyclo-thiazeno Complexes of Molybdenum and Tungsten. The Crystal Structure of A sPh4[WCl4(N 3S2)]  
 Abstract    The dark brown cyclo-thiazeno com plexes [M oCl3(N 3S2)]2 and [WC13(N 3S2)]2 are obtained by 
  Reference    Z. Naturforsch. 39b, 1680—1685 (1984); eingegangen am 14. Juli 1984 
  Published    1984 
  Keywords    Cyclo-thiazeno C om plexes, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-1680.pdf 
 Identifier    ZNB-1984-39b-1680 
 Volume    39 
48Author    Udo Demant, Elke Conradi, Ulrich Müller, Kurt DehnickeRequires cookie*
 Title    Formamidinhim-Hexachloroferrat(III) Synthese und Kristallstruktur Formamidinium-Hexachloroferrate(III) Synthesis and Crystal Structure  
 Abstract    [HC(NH 2) 2 ] 3 FeCl 6 was obtained together with other products from the reaction of S 4 N 4 with HCl in H 2 CC1 2 in the presence of FeCl 3 . Its crystal structure was determined from X-ray diffraction data (473 in-dependent observed reflexions, R = 0.047). Lattice constants: a = 961.6, c — 876.4 pm; tetragonal, space group P4 2 /m, Z = 2. Of the two crystallo-graphically independent formamidinium ions HC(NH 2) 2 ®, one exhibits positional disorder; the other one has C—N bond lengths of 128 pm. The FeCl 6 30 ions have symmetry C 2h , but the deviation from O h is small. 
  Reference    Z. Naturforsch. 40b, 443—445 (1985); eingegangen am 6. November 1984 
  Published    1985 
  Keywords    Formamidinium-Hexachloroferrate(III), Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0443_n.pdf 
 Identifier    ZNB-1985-40b-0443_n 
 Volume    40 
49Author    Wolfgang Gerhartz, Friedrich-Wilhelm Grevels, WernerE. Klotzbücher, ErnstA. Koerner Von Gustorf, RobinN. PerutzRequires cookie*
 Title    Low-Temperature Matrix Photochemistry of (f/ 4 -Diene)tetracarbonylchromium Complexes  
 Abstract    Photolysis of (^ 4 -diene)Cr(CO) 4 complexes (diene = butadiene, trans,trans-2,4-hexadiene, 2,3-dimethylbutadiene) in Ar, N 2 , and CO matrices at 10-12 K was monitored by infrared and UV-Vis spectroscopy. In argon and dinitrogen matrices loss of CO ist the predominant photoreaction. The resulting fac-(rf-diene)Cr(CO) 3 can take up N 2 from the matrix to form (?7 4 -diene)Cr(CO) 3 (N 2). In the case of the hexadiene complex this process requires matrix an-nealing subsequent to photolytic loss of CO. Photolysis in CO matrices, by contrast, results in stepwise displacement of the diene ligand, yielding (/7 2 -diene)Cr(CO) 5 and ultimately Cr(CO) 6 . 
  Reference    Z. Naturforsch. 40b, 518—523 (1985); received November 13 1984 
  Published    1985 
  Keywords    Matrix Isolation, Photochemistry, Carbonylchromium Diene Complexes, IR Spectra 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0518.pdf 
 Identifier    ZNB-1985-40b-0518 
 Volume    40 
50Author    Thomas Godemeyer, Alexander Berg, Hans-Dieter Groß, Ulrich Müller, Kurt DehnickeRequires cookie*
 Title    ji-Nitridokomplexe von Wolfram(VI) Die Kristallstruktur von PPh4[W2NCl10] /<-Nitrido Complexes of Tungsten(VI) The Crystal Structure of PPh4[W2NCl10]  
 Abstract    W2NC19 was obtained as a brilliant red crystal powder from tungsten hexachloride and tris(trim ethylsilyl)am ine. A ccording to its IR spectrum it has dimeric m olecules [W 2NC19]2 with bridging chlorine atom s. Its reaction with tetraphenylphosphonium chloride yields PPh4[W2N C l10], and with phosphorus oxide chloride W 2NCl9 O PCl3 is obtained; both are soluble in dichlorom ethane. The crystal structure of PPh4[W2N C l10] was determined_ by X-ray diffraction (2521 observed reflexions. R = 0.065). Crystal data: triclinic, space group P I , Z = 2, a = 1125.7, b — 1278.2, c = 1347.8 pm, a = 110.08, ß = 94.55, y = 111.55°. The structure consists o f PPh4® ions which are arranged to (PPh4®)2 pairs about inversion centres, and o f [W2N C l10]e anions. The latter possess an alm ost linear W NW group (173°) with slightly different WN bond lengths o f 179 and 188 pm corresponding to double bonds. Each tungsten atom has an octahedral coordination. The WC1 bonds trans to the nitrido ligand are about 9 pm longer than the bonds in the cis positions. 2. Synthesen und IR-Spektren der /i-Nitridokomplexe W2NC19 erhält man gemäß Gl. (1) durch Um set­ zung von Wolframhexachlorid mit Tristrimethylsilyl-amin in Trimethylchlorsilan als Lösungsmittel: 2 WC16 + N(SiMe3) 3 < 9 °C> W2NC19 + 3 Me3SiCl (1) Zur Herstellung eines reinen Produktes hat sich die Anwendung von Trimethylchlorsilan, in dem sich WC16 beträchtlich löst, als ebenso bedeutsam erwie­ sen wie die Kühlung des Reaktionsansatzes < 9 °C. Erhöht man die Temperatur, so findet bereits bei 20 °C langsam und ausschließlich die Bildung des auch auf andere Weise zugänglichen WNC13 [1] statt. Wählt man in diesem Fall das Mengenverhältnis der Reaktanden nach (1), so läßt sich schließlich die Hälfte des WC16 zurückgewinnen. Bei Anwendung molarer Mengen 1:1 erhält man direkt reines WNC13: WC16 + N(SiM e3) 3 2 0 °C > WNC13 + 3 Me3SiCl (2) Für den Mechanismus der Reaktion (1) nehmen wir einen stufenweisen Verlauf an, bei dem sukzessive Trimethylchlorsilan abgespalten wird. Erstes mögli­ ches Zwischenprodukt wäre dann Cl5WN(SiMe3)2, das wir allerdings nicht isolieren konnten. Die A b­ spaltung eines zweiten Trimethylchlorsilans führt 0 ® dann zur Bildung des Imids C14W =N —SiMe3, das 
  Reference    Z. Naturforsch. 40b, 999—1004 (1985); eingegangen am 4. April 1985 
  Published    1985 
  Keywords    «-Nitrido C om plexes Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0999.pdf 
 Identifier    ZNB-1985-40b-0999 
 Volume    40 
51Author    Kurt Dehnicke, Josef Schmitte, Dieter FenskeRequires cookie*
 Title    Tetrazido-Nitrido-Molybdat(VI); Darstellung, IR-Spektrum und Kristallstruktur von AsPh4[MoN(N3)4] Tetrazido-nitrido-molybdate(VI); Preparation, IR Spectrum and Crystal Structure of AsPh4[MoN(N3)4]  
 Abstract    The complex AsPh4[MoN(N3)4] is prepared by the reaction of AsPh4[MoNCl4] with silver azide in dichloromethane suspension in the presence of dry sodium sulfate. The IR spectrum indicates an Mo=N group and four covalently bonded N3 groups for the [MoN(N3)4] e anion. AsPh4[MoN(N3)4] crystallizes in the triclinic space group P1 with two formula units in the unit cell. The crystal structure was solved by X-ray diffraction methods (R = 0,038; 4049 independent reflexions). The structure consists of AsPh4® cations and [MoN(N3)4] e anions. The short MoN bond length of the nitrido ligand (163 pm) corresponds to an Mo = N triple bond. The steric effects of the lone pairs of the a-N atoms of the azido groups with the MoN ligand cause a propellerlike twisted conformation of the four azido groups. 
  Reference    Z. Naturforsch. 35b, 1070—1074 (1980); eingegangen am 15. Mai 1980 
  Published    1980 
  Keywords    Preparation, Tetrazido-nitrido-molybdate(VI), Crystal Structure, IR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1070.pdf 
 Identifier    ZNB-1980-35b-1070 
 Volume    35 
52Author    Tetrachloroplatinate, AsparaginePhilippe Arrizabalaga, Paule Castan, Jean-Pierre LaurentRequires cookie*
 Title    Platinum Blues -a Study of the Interaction between Potassium  
 Abstract    Potassium tetrachloroplatinate and asparagine form a paramagnetic complex in aqueous solution. This complex which displays a blue green color has been studied by ESR and IR spectroscopy. The ESR spectra are interpreted to be due to tervalent platinum in a low spin d 7 configuration. The IR data suggest that the doubly deprotonated ligand is co-ordinated through the COO -and CONH -groups. 
  Reference    Z. Naturforsch. 35b, 1508—1510 (1980); received August 11 1980 
  Published    1980 
  Keywords    Potassium Tetrachloroplatinate, Platinum (III), Asparagine, ESR Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1508.pdf 
 Identifier    ZNB-1980-35b-1508 
 Volume    35 
53Author    P. Io, K. Oziej, M. Anfred, M. UtterRequires cookie*
 Title    Conformational Studies of Synthetic Polyethylene Glycol Bound Substance P and its Lower Analogues  
 Abstract    Institute o f Organic Chemistry, Johannes-G utenberg-U niversität, D -6500 Mainz H ans-U lrich G rem lich, G ü n te r H ölzem ann M edical Chemistry Research D e p t., E. M erck, The synthesis o f Substance P (SP) bound at the C-terminal m ethionine to polyethylene glycol m onom ethyl ether (M -P E G) is described. SP-PEG-M is obtained in good yield by the liquid-phase peptide synthesis. G el perm eation chromatography reveals that aggregated forms o f the PEG -bound peptides are absent in CHC13. CD and IR spectra point to a /3-turn located at the N-terminal part o f SP-PEG -M . In binding studies and in vivo assays the described com pounds are devoid of biological activity. 
  Reference    Z. Naturforsch. 40b, 1570—1574 (1985); received June 19 1985 
  Published    1985 
  Keywords    Substance P, Polyethylene G lycol, C D, IR Spectra, /3-Turn 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-1570.pdf 
 Identifier    ZNB-1985-40b-1570 
 Volume    40 
54Author    HeribertW. Adle, Elke Conradi, Ulrich Müller, Kurt DehnickeRequires cookie*
 Title    Cyclothiazeno-oxo-diazidowoIframat(VI) Die Kristallstruktur von (AsPh4)2[W(N3S2)(0)(N3)2]2 Cyclothiazeno Oxodiazidotungstate(VI) The Crystal Structure of (A sPh4)2[W (N3S2)(0 )(N 3 )2]2  
 Abstract    A new, im proved m ethod of synthesis for the cyclothiazeno complex A sPh4[WCl4(N 3S2)] con­ sists of the reaction of Na2W 0 4 with molten trithiazyl chloride (NSC1)3 followed by treatm ent with A sPh4Cl in C H 2C12. Through the reaction with silver azide suspended in C H 2C12 in the presence of m oisture, black crystalline (A sPh4)2[W(N3S2)(0)(N 3)2]2 is obtained. Its IR spectrum and its crys­ 
  Reference    Z. Naturforsch. 40b, 1626—1630 (1985); eingegangen am 28. A ugust 1985 
  Published    1985 
  Keywords    Cyclothiazeno O xodiazidotungstate(V I), Synthesis, IR Spectra, Crystal Structure 
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 Identifier    ZNB-1985-40b-1626 
 Volume    40 
55Author    Wolfgang Willing, Ruth Christophersen, Ulrich Müller, K. Urt DehnickeRequires cookie*
 Title    Synthese und Kristallstruktur von VBr2(N3S2)(Pyridin) 2 Synthesis and Crystal Structure of VBr2(N3S2)(pyridine)2  
 Abstract    VBr2(N 3S2)(pyridine)2 is obtained in form o f brown-black, moisture sensitive crystals by the 
  Reference    Z. Naturforsch. 41b, 831 (1986); eingegangen am 22. April 1986 
  Published    1986 
  Keywords    Cyclo-thiazeno Vanadium Dibrom ide D ipyridine, Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/41/ZNB-1986-41b-0831.pdf 
 Identifier    ZNB-1986-41b-0831 
 Volume    41 
56Author    A. E. Lavat, S. B. Etcheverry, E. J. BaranRequires cookie*
 Title    Kristallographisches und spektroskopisches Verhalten einiger gemischter Phosphat/Vanadat-Fluoroapatite Crystallographic and Spectroscopic Behaviour of Some Mixed Phosphate/Vanadate Fluoroapatites  
 Abstract    Crystallographic data for m ixed phosphate/vanadate fluoroapatites o f the type M 1o(P0 4)6_J(V 0 4)AF2 (with M = Ca, Sr, Ba and x = 1—3) have been obtained from X-ray powder data. The only structural effect observed is a continuous increase of unit cell dim ensions with increased vanadate incorporation. The IR and Raman spectra show that the V 0 43 incorporation has a negligible effect on the strength of the P —O bonds, although a small bond weakening for both tetrahedral oxoanions is observed as the unit cell volum e increases. The results are com par­ able to those reported earlier for similar mixed hydroxyapatites and suggest that the fluoroapatite lattice can be considered as a good "m odel" for the vertebrate hard tissues. 
  Reference    Z. Naturforsch. 41b, 987 (1986); eingegangen am 15. April 1986 
  Published    1986 
  Keywords    Mixed A patites, Crystal Data, IR Spectra, Raman Spectra 
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 Identifier    ZNB-1986-41b-0987 
 Volume    41 
57Author    Hidenari Inoue, Takashi Nakagome, Takeshi Kuroiwa, Tsuneo Shirai, Ekkehard FluckRequires cookie*
 Title    Infrared, 57 Fe Mössbauer, and 31 P NMR Spectroscopic Characterization of Fe(CO) 4 L (L = Phosphine and Phosphite)  
 Abstract    A series of trigonal bipyramidal Fe(CO) 4 L complexes has been prepared and characterized by infrared, 57 Fe Mössbauer and 31 P NMR spectroscopy. A linear correlation, with a negative slope, between the CO stretching frequencies and the isomer shifts demonstrates that the triple bond nature of the carbonyl ligands is strengthened with increasing iron-to-phosphorus back donation. The linear dependence of the quadrupole splittings on the isomer shifts with a positive slope has revealed that the cr-donor capability of the phosphine or phosphite ligand is offset by the ^ • -acceptor capability. The formation of Fe(CO) 4 L complexes from the corresponding free ligands is accompanied by a downfield shift of 31 P NMR chemical shifts. The coordination shifts are linearly correlated with the Mössbauer isomer shifts. 
  Reference    Z. Naturforsch. 42b, 573—578 (1987); eingegangen am 8. Januar 1987 
  Published    1987 
  Keywords    Phosphinetetracarbonyliron, Phosphitetetracarbonyliron, IR Spectra, 31 P NMR Spectra, 57 Fe Mössbauer Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0573.pdf 
 Identifier    ZNB-1987-42b-0573 
 Volume    42 
58Author    H. G. Alt, H. E. EngelhardtRequires cookie*
 Title    Bis-acetylene Complexes of Niobium and Tantalum  
 Abstract    The photo-induced reaction of C 5 Me 5 M(CO) 4 complexes (M = Nb, Ta) with excess alkynes R'C 2 R : (R\ R 2 = H, Me, Ph, Hex) in pentane solution results in the formation of the bis-acetylene complexes C 5 Me 5 M(R'C 2 R 2) 2 CO. In these complexes the jr-bonded acetylene ligands behave formally as three electron ligands. 
  Reference    Z. Naturforsch. 42b, 711—714 (1987); eingegangen am 10. Dezember 1986/23. Januar 1987 
  Published    1987 
  Keywords    Bis-acetylene Complexes of Niobium and Tantalum, IR Spectra, NMR Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0711.pdf 
 Identifier    ZNB-1987-42b-0711 
 Volume    42 
59Author    Lothar Weber, Georg MeineRequires cookie*
 Title    Zur Reaktivität von Diphosphenylkomplexen des Eisens und Rutheniums gegenüber Tetracarbonylnickel Transition Metal Substituted Diphosphenes, VI [1] On the Reactivity of Diphosphenyl Complexes of Iron and Ruthenium towards Tetracarbonyl Nickel  
 Abstract    The diphosphenyl complexes (?/ 5 -CsMe0(CO 2)M-P = P-Ar (8) (M = Fe, Ru; Ar = 2,4,6-rm-BU,C 6 H 2) react with excess Ni(CO) 4 to yield the adducts (77 5 -C 5 Me 5)(CO) 2 M[Ni(CO) 3 ]P=PAr (9). The products have been characterized by elemental analysis as well as by spectroscopic data (IR. 'H, 13 C, 31 P NMR). 
  Reference    Z. Naturforsch. 42b, 774—776 (1987); eingegangen am 26. Januar 1987 
  Published    1987 
  Keywords    Metal Substituted Diphosphenes, Tetracarbonyl Nickel, NMR Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0774.pdf 
 Identifier    ZNB-1987-42b-0774 
 Volume    42 
60Author    Dieter Fenske, Eberhard Böhm, Kurt Dehnicke, Joachim SträhleRequires cookie*
 Title    N-TrimethylsilyMminotriphenylphosphoran-Kupfer(II)-chlorid, (Me 3 SiNPPh 3 * CuCl 2 ]2 Synthese und Kristallstruktur N-Trimethylsilyl-iminotriphenylphosphorane Copper(II) Chloride, [Me 3 SiNPPh 3 * CuCl : ] 2 Synthesis and Crystal Structure  
 Abstract    The title compound has been prepared by the reaction of N-trimethylsilyl-iminotriphenylphos-phorane with copper(II) chloride in boiling CCl 4 /C 2 H 5 OH, and forms moisture sensitive crystals, which are green in transmittance and black in reflexion. [Me 3 SiNPPh 3 • CuCl 2 ] 2 was characterized by its IR spectrum as well as by a crystal structure determination (4197 observed, independent reflexions, R = 0.049). The lattice dimensions are at 20 °C: a = 1102.7. b = 1407.3. c = 1560.2 pm; ß = 94.27°; space group P2,/« with two formula units in the unit cell. The complex consists of centrosymmetric, dimeric molecules with a planar Cu 2 Cl 2 ring (Cu —CI bond lengths 229 and 231 pm). A terminally bonded CI atom (Cu —CI = 221 pm) and the N atom of the Me,SiNPPh 3 ligand (Cu —N = 198.5 pm) complete the coordination number four of the nearly planar surroundings of the Cu atoms. 
  Reference    (Z. Naturforsch. 43b, 1 [1988]; eingegangen am 4. September 1987) 
  Published    1988 
  Keywords    N-Trimethylsilyl-iminotriphenylphosphorane Copper(II) Chloride, Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0001.pdf 
 Identifier    ZNB-1988-43b-0001 
 Volume    43 
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