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1Author    Dieter Bauernschmitt, Helmut Behrens, Jochen EllermannRequires cookie*
 Title    Hy drido -carbonyl -, Deuterido -carbonyl - und Carbamoyl-carbonyl-cobalt(I)-Komplexe des Tetrakis(diphenylphosphinomethyl)metlians [1] Hydrido-carbonyl, Deuterido-carbonyl and Carbamoyl-carbonyl-cobalt(I) Complexes of Tetrakis(diphenylphosphinomethyl)methane [1]  
 Abstract    [CO(CO)2(R2PCH2)3CCH2PR2][CO(CO)4] (R = C6H5) was synthesized in a simple manner from Co2(CO)s and the tetratertiary phosphine C[CH2P(C6H5)2]4, which acts only as a tridentate ligand. [Co(CO)2(R2PCH2)3CCH2PR2][Co(CO)4] reacts with NH4PF6, NaBH4, NaBD4 or liquid ammonia at 20 °C to [Co(CO)2(R2PCH2)3CCH2PR2]PF6, CoH(CO)2(R2PCH2)2C(CH2PR2 • BH3)2, CoD(CO)2(R2PCH2)2C(CH2PR2 • BD3)2 or Co(CO)(CONH2)(R2PCH2)3CCH2PR2. In liquid ammonia [Co(CO)2(R2PCH2)3CCH2PR2][Co(CO)4] at 60 °C yields the hydride CoH(CO)(R2PCH2)3CCH2PR2. The new compounds were characterized, as much as possible, by their IR, Raman and 1 H NMR data. 
  Reference    Z. Naturforsch. 34b, 1362—1368 (1979); eingegangen am 5. Juni 1979 
  Published    1979 
  Keywords    Cobaltcarbonyl Hydrides, Cobaltcarbonyl Carbamoyl Complex, Tetratertiary Phosphine, IR Spectra, Raman Spectra 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1362.pdf 
 Identifier    ZNB-1979-34b-1362 
 Volume    34