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21	Author	Ekkehard Lindner, Robert Speidel	Requires cookie*
	Title	Neuartige basische Liganden für die homogenkatalytische Methanolcarbonylierung, XXI [1] Synthese und Eigenschaften von (Ether-Phosphan)-Platin-Komplexen Novel Basic Ligands for the Homogenous Catalytic Methanol Carbonylation, XXI [1] Synthesis and Properties of (Ether-Phosphane) Platinum Complexes
	Abstract	The (ether-phosphane) complexes m -C l2Pt(Ph: P ~ D)2 (2a, b) [D = C H 2C4H 70 (a). C H 2C4H 70 2 (b)] are obtained by reaction of Ph2P ~ D (la , b) with either K2PtCl4 or Cl2Pt(CO D) (C O D = 1,5-cyclooctadiene). Both Cl ^anions are abstracted from 2a, b using A gSbF(1 to give the cationic bischelate complexes [Pt(Ph2P D)2][SbFh]2 (5a, b). The stepwise cleavage and reform a tion of Pt —O bonds in (ether-phosphane) platinum complexes is dem onstrated bv the sequence 5a —> [rä -(P h 2P D)(Ph2P ~D)P tC l][S bF 6] (6 a) -* [rra«5-(Ph2P ~ D)2PtC O (C l)][SbF6] (7 a) -* 5a, when 5a, 6 a, and 7a are reacted with KC1. CO, and AgSbF,,, respectively. Reduction of 2a with N aB H 4 results in the form ation of rra/2s-H 2Pt(Ph2P ~ D)2 (4a). In the presence of HC1 2a js re formed. Excess N aBH 4 or heating of 4a yields the bischelate platinum(O) complex Pt(P h: P D)2 (3a), which is also jso lated by reduction of 2a with sodium amalgam. A general method for obtaining P t(P h2P D)2 (3 a —c) [D = C H 2C H 2O C H , (c)] is the substitution of C O D in P t(C O D)2 by the ether-phosphanes l a —c. The structures and bonding properties of the com pounds 2 —7 are discussed on the basis of their 31P {1H } NMR and IR spectra.
	Reference	Z. Naturforsch. 44b, 437—443 (1989); eingegangen am 20. D ezem ber 1988
	Published	1989
	Keywords	Ether-Phosphanes Platinum Complexes, 3iP {'H} NMR Spectra, IR Spectra
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	TEI-XML for	default:Reihe_B/44/ZNB-1989-44b-0437.pdf
	Identifier	ZNB-1989-44b-0437
	Volume	44

22	Author	Reiner Figge, Claus Friebel, U. Te Patt-Siebel, Ulrich Müller, Kurt Dehnicke	Requires cookie*
	Title	Nitridokomplexe von Molybdän(V); Synthesen, IR-und EPR-Spektren. Die Kristallstruktur von [Na(15-Krone-5)Na(THF)]2[MoNCI3 THF]4-2THF Nitrido Complexes of M olybdenum (V ); Syntheses, IR , and EPR Spectra. Crystal Structure of [N a(15-Crow n-5)N a(TH F)]2[MoNCl3-THF]4-2T H F
	Abstract	Nitrido C om plexes o f M olyb denu m (V),
	Reference	Z. Naturforsch. 44b, 1377—1384 (1989); eingegangen am 30. Mai 1989
	Published	1989
	Keywords	Syntheses, IR Spectra, EPR Spectra, Crystal Structure
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	Identifier	ZNB-1989-44b-1377
	Volume	44

23	Author	Michael Schäfer, Jürgen Pebler, Beatrice Borgsen, Frank Weller, K. Urt Dehnicke	Requires cookie*
	Title	21Sb-Mössbauer-spektroskopische und strukturchemische Untersuchungen an Kronenetherkomplexen SbX3(15-Krone-5) mit X = F, Cl, Br, I. Eine Analyse der Orbitalbesetzungszahlen 12lSb-M össbauer-Spectroscopic and Structural Investigations on Crown Ether Complexes SbX3(15-Crown-5) with X = F, Cl, Br, I. A Population Analysis Crown Ether C om plexes SbX3(15-crown-5)
	Abstract	The crown ether complexes SbX3(15-crown-5) with X = F, Cl, Br, and I have been prepared by reactions o f 15-crown-5 with the corresponding antimony trihalides in acetonitrile solu tions. The com pounds were characterized by IR spectroscopy as well as by l21Sb-M össbauer spectroscopy. A m ethod o f orbital population analysis utilizing both M össbauer isomer shifts and quadrupole coupling has been developed for Sb(III) antimony halides and their crown ether com plexes. SbF 3(l 5-crown-5) was also characterized by an X-ray structure determination: Space group P 2 ,/«, Z = 4, 3628 observed unique reflexions, R = 0.032. Lattice dim ensions at 19 °C: a = 891.54(6), b = 1277.26(6), c = 1277.66(7) pm, ß = 95.029(4)3. The com plex has a molecular structure in which the antimony atom is surrounded by three F-atom s with mean bond lengths o f 192.4 pm and by the five oxygen atom s o f the crown ether molecule with mean bond lengths o f 293.9 pm.
	Reference	Z. Naturforsch. 45b, 1243—1250 (1990); eingegangen am 5. März/9. Mai 1990
	Published	1990
	Keywords	Syntheses, IR Spectra, 12lSb-M össbauer Spectra, Crystal Structure
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	Identifier	ZNB-1990-45b-1243
	Volume	45

24	Author	Gabriele Schatte, Helge Willner	Requires cookie*
	Title	Die Wechselwirkung von N 3F mit Lewis-Säuren und HF. N 3F als möglicher Vorläufer für die Synthese von N 3+-Salzen The Interaction of N 3F with Lewis-Acids and HF. N 3F as Possible Precursor for the Synthesis of N 3+ Salts
	Abstract	Triazadienyl fluoride, N 3F, forms stable adducts with BF3 and AsF5 at low temperatures, as demonstrated by infrared measurements. The Lewis acids are bonded to the Na-atom of N 3F, as deduced from the data for 15N-isotopically enriched N 3F. The basicity of N 3F is comparable to that of ethine and ethene, according to the HF stretching frequency of the N 3F/HF complex isolated in an argon matrix. Despite the low NF bond energy (<150 kJ/mol), abstraction of the fluoride ion and formation of an N 3+ salt was not possible. The different behavior of N 3F and C1N3 towards Lewis acids is discussed.
	Reference	Z. Naturforsch. 46b, 483—489 (1991); eingegangen am 3. September 1990
	Published	1991
	Keywords	Triazadienyl Fluoride, IR Spectra, Lewis Acids, Proton Affinity
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	TEI-XML for	default:Reihe_B/46/ZNB-1991-46b-0483.pdf
	Identifier	ZNB-1991-46b-0483
	Volume	46

25	Author	Rolf Minkwitz, Volker Gerhard, Frau	Requires cookie*
	Title	Über Dimethylhaloniumsalze -CH3C1CH3+M F6 , CH3BrCH3+M F6 , CH3ICH3+MF6" -und Dimethylmethylendiiodoniumsalze CH3ICH2ICH32+(M F6 )2 (M = As, Sb)
	Abstract	The dimethylhalonium salts (C H 3)2X +A~ (X = Cl, Br, I; A " = A sF 6-, SbF6~, Sb2F n ~) are synthesized by methylation o f the corresponding methylhalides C H 3X or dihalomethanes C H 2C12 and CH2Br2 in the system S 0 2/C H 3F /M F 5. The analogous reaction o f C H 2I2 results in the formation o f dimethylmethylendiiodonium hexafluorometallates C H 3IC H ,IC H 32+(M F 6")2 (M = As, Sb). The salts are characterized by Raman-, IR-and N M R-spectroscopy.
	Reference	Z. Naturforsch. 46b, 561—5 (1991); eingegangen am 21. Juni 1990
	Published	1991
	Keywords	Preparation, Raman Spectra, IR Spectra, N M R Spectra
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	Identifier	ZNB-1991-46b-0561
	Volume	46

26	Author	R. Olf Minkwitz, VolkerG. Erhard	Requires cookie*
	Title	Über die Reaktionen der Halogene Cl2, Br2 und I2 mit CH3O S O +M F6 (M = As, Sb)
	Abstract	Chlorine reacts with C H 3O SO +M F6" (M = As, Sb) at 298 K to form AsC14 +A sF 6" and SbCl4 +Sb2Cl2F9~, respectively. The analogous reactions with bromine at 233 K result in the formation o f (C H 3)2 Br+A sF 6~ and Sb2F,,~. With iodine, the new methyliodonium salts (C H 3 I2)n"+(M F 6~)n (M = As, Sb) with yet unknown constitution are obtained.
	Reference	Z. Naturforsch. 46b, 1470—1472 (1991); eingegangen am 11. März 1991
	Published	1991
	Keywords	Preparation, IR Spectra, N M R Spectra
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	Identifier	ZNB-1991-46b-1470
	Volume	46

27	Author	Rene Wollert, SigridW. Ocadlo, K. Urt Dehnicke, Helmut Goesmann, Dieter Fenske	Requires cookie*
	Title	Die Kristallstrukturen von (PPh4)2 [TiCl3 (NSiMe3) ] 2 * CH3CN und (PPh4)2 [TiCl4(OSPCl2) ] 2 The Crystal Structures of (PPh4)2[TiCl3(NSiM e3)]2 -C H 3CN and (PPh4)2[TiCl4(OSPCl2)]2
	Abstract	(PPh4)2[TiCl3(N SiM e3)]2 C H 3CN has been prepared from [TiCl^NSiM ej)]^ with PPh4Cl in acetonitrile solution as yellow crystals. The com pound crystallizes in the triclinic space group P 1 with one formula unit per unit cell, 3447 observed unique reflections, R = 0.053. Lattice dimensions at 200 K: a = 1030(1), b = 1253(1), c = 1374(1) pm, a = 77.46(8)°, ß = 73.93(8)°, y = 69.99(9)°. The structure consists o f PPh4+ ions and centrosymmetric dimeric anions [TiCl3(N SiM e3)]2~, in which pentacoordinate titanium atom s are associated via the nitrogen atoms o f the silylimido groups. (PPh4)2[TiCl4(OSPCl2)]2 has been prepared by the reaction o f PPh^fOSPClJ with titanium tetrachloride in C H 2C12 solution as orange crystals. (Space group P I , Z = 1, 3242 observed unique reflections, R = 0.033). Lattice dim ensions at 193 K: a = 1114.8(2), b = 1190.6(2), c = 1218.7(2) pm, a = 72.18(1)°, ß = 85.45(1)°, y = 69.19(1)°. The structure consists o f PPh4+ ions and centrosymmetric dimeric anions [TiCl4(O SPCl2)]^~, in which hexacoordinate titanium atom s are associated via two chlorine atoms. The OSPCl2_ group is coordinated via the oxygen atom.
	Reference	Z. Naturforsch. 47b, 1386—1392 (1992); eingegangen am 9. März 1992
	Published	1992
	Keywords	Dimeric Titanium Complexes, Synthesis, IR Spectra, Crystal Structure
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	Identifier	ZNB-1992-47b-1386
	Volume	47

28	Author	Michael Plate, Peter Hofacker, WernerM. Assa, Birgit Schwarz, Bernhard Neumüller, Kurt Dehnicke	Requires cookie*
	Title	Synthese und Kristallstrukturen der Wolfram(VI)-Alkinkomplexe \|WCl4(P h -C = C -I)(T H F )l und [WCl4( P h -C = C -T e -C 4H9)(THF)\| Synthesis and Crystal Structures o f the Tungsten(VI) Alkyne Complexes [WCl4(P h -C = C -I)(T H F )] and [WCl4( P h -C = C -T e -C 4H 9)(THF)]
	Abstract	[WCl4(P h -C = C -I)(T H F)] has been prepared by the reaction o f mrns-[WCl4(SEt2)2] with P h -C = C -I in TH F solution, whereas [WCl4(P h -C = C -T e -n C 4H 9)(THF)] has been syn thesized by the reaction o f P h -C = C -T e -« C 4H 9 with tungsten hexacloride in the presence o f C2C14 and THF. Both complexes were characterized by IR spectroscopy and by crystal struc ture determinations. [WCl4(P h -C = C -I)(T H F)]: Space group P 2,/c, Z = 4, 2617 observed unique reflections, R = 0.064. Lattice dimensions at -7 0 °C: a = 1518.2(3), b = 714.5(1), c = 1540.0(3) pm, ß = 90.09(3)°. [WCl4(P h -C = C -T e -« C 4H9)(TH F)]. Space group P 1, Z = 2, 3911 observed unique reflec tions, R = 0.067. Lattice dimensions at 20 °C: a = 844.0(3), b = 974.6(4), c = 1002.4(3) pm, a = 76.00(4),/? = 105.14(1), y = 82.03(3)°. Both complexes have molecular structures, in which the tungsten atom s are seven-coordi nate by four chlorine ligands, by the two alkyne carbon atom s, and in trans position to the latter by the oxygen atom o f the T H F molecule. The WC bond lengths are 198 and 200(1) in the telluro complex and 206 and 196(1) pm in the iodine derivative.
	Reference	Z. Naturforsch. 48b, 1105—1111 (1993); eingegangen am 21. April 1993
	Published	1993
	Keywords	Tungsten Alkyne Complexes, Synthesis, IR Spectra, Crystal Structure
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	Identifier	ZNB-1993-48b-1105
	Volume	48

29	Author	Frank Weller, Fritjof Schmock, Kurt Dehnicke, Kurt Findeisen Bayer-Werk	Requires cookie*
	Title	Synthese, IR-Spektrum und Kristallstruktur von 1.3.5-Trichlortriazinium-hexachloroantimonat, [HC3N3C13]SbCl6 Synthesis, IR Spectrum and Crystal Structure of 1.3.5-Trichlortriazinium Hexachloroantim onate, [HC3N3Cl3]SbCl6
	Abstract	,3,5-Trichlortriazinium hexachloroantimonate has been prepared by the reaction of CCl2 = N-COCl with antimony pentachloride in boiling dichloromethane. The compound was characterized by IR spectroscopy and by a crystal structure determination. [HC3N3Cl3]SbCl6 crystallizes in the monoclinic space group P 2 Jn with four formula units per unit cell. 2503 observed unique reflections, R = 0.029. Lattice dimensions at 19 °C: a = 1314.1(1), b = 958.2(1), c = 1329.1(1) pm, ß = 117.113(5)°). The compound forms ion pairs via a linear N -H • • • Cl bridge, thus distorting the SbCl6~ ion from octahedral geometry. The C3N3 skeleton of the [HC3N3C13]+ ion is nearly planar, but the hydrogen atom lies about 30 pm out of this plane.
	Reference	Z. Naturforsch. 49b, 360—364 (1994); eingegangen am 3. November 1993 1.3.
	Published	1994
	Keywords	5-Trichlortriazinium Salt, Synthesis, IR Spectra, Crystal Structure 1
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	Identifier	ZNB-1994-49b-0360
	Volume	49

30	Author	Z. Naturforsch	Requires cookie*
	Title
	Abstract	Single crystals of (Me3Sn)3CCN were obtained by the reaction of tris(trimethylstannyl)amine with boiling acetonitrile in the presence of potas sium fluoride and trimethylarsane. The compound has been characterized by IR spectroscopy and by a crystal structure determination. Space group
	Reference	Z. Naturforsch. 52b, 145—148 (1997); eingegangen am 7. Oktober 1996
	Published	1997
	Keywords	Tin Compound, Synthesis, IR Spectra, Crystal Structure
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	Identifier	ZNB-1997-52b-0145_n
	Volume	52

31	Author	N.M U Rq, U. Iza3, S.G M Ancaa	Requires cookie*
	Title	On the Incorporation o f Li(I) into the Fluoroapatite Lattice
	Abstract	a Instituto de Q ufm ica A nalftica, Facultad de Bioqufm ica, Q ufm ica y Farmacia, U niversidad N acional de Tucum än, 4000-Tucum an, A rgen tina b C entro de Q ufm ica Inorgänica (C E Q U I N O R), Facultad de C iencias Exactas, U n iversidad N acional de La Plata, C. C orreo 962, In attem pts to incorporate the L i(I) cation into the C a(II) position s o f the fluoroapatite lattice it has been sh ow n that the unit cell b eco m es increasingly distorted with the increase o f lithium concentration. C rystallographic data have been obtained from X-ray pow d er data. The infrared spectra o f th ese su bstitu ted apatites sh ow that the Li(I) incorporation has a n egligible effect on the strength o f the P-O bonds.
	Reference	Z. Naturforsch. 52b, 1281 (1997); received July 2 1997
	Published	1997
	Keywords	Lithium, F luoroapatite, Crystal D ata, IR Spectra
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	Identifier	ZNB-1997-52b-1281_n
	Volume	52

32	Author	Wolfgang Beck, ThomasM. Klapötke	Requires cookie*
	Title	and IR Frequencies of the Anionic Fulminate Complexes [Co(CNO)6]3-, [Ni(CNO)4]2-, [Zn(CNO)4]2-, [Pt(CNO)4]2", [Au(CNO)2] ' and [Hg(CNO)4]2
	Abstract	The structural parameters and IR frequencies of the following anionic fulminate complexes were computed at the density functional BPW91 level of theory using a 6-31++G(2d) basis for C, N, O, Co, Ni, and Zn and quasi-relativistic ECP60MWB core potentials for Pt, Au and Hg: [Co(CNO)6]3-(Oh), [Ni(CNO)4]2-(D 4h), [Zn(CNO)4]2-(Td), [Pt(C N 04]2-(D 4h), [Au(CNO)2]~ (£>xh) and [Hg(CNO)4]2-(Td). The structures were optimised within the symmetries stated above and were found to represent true minima (number of imaginary frequencies, NIMAG = 0). The agreement between the calcu lated structural parameters and characteristic asymmetric and symmetric CNO stretching fre quencies is very good for all complexes.
	Reference	Z. Naturforsch. 56b, 1376—1378 (2001); received October 16 2001
	Published	2001
	Keywords	DFT Calculations, Fulminate Complexes, IR Spectra
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	Identifier	ZNB-2001-56b-1376_n
	Volume	56

33	Author	M. Maeda, T. Ito, M. Hori, G. Johansson	Requires cookie*
	Title	The Structure of Zinc Chloride Complexes in Aqueous Solution
	Abstract	The structure of zinc chloride complexes with different ratios of chloride to zinc, formed in concentrated ZnCl 2 aqueous solutions, were determined from large-angle X-ray scattering using concentrations of the chloride complexes estimated by complementary Raman spectroscopic mea-surements. The highest chloro complex, [ZnCl 4 ] 2 ~, is tetrahedral with a Zn-Cl bond length of 2.294(4) Ä. The trichloro complex, [ZnCl 3 ]~, which coordinates one water molecule, is pyramidal with the Cl-Zn-Cl angle 111°. The Zn-Cl and the Zn-H 2 0 bonds are 2.282(4) and 1.9 A, respec-tively. The two lower complexes, [ZnCl 2 ] and [ZnCl] + , cannot be separated by Raman spectra. o The average Zn-Cl distance in these complexes is 2.24 Ä, and the average Zn-H 2 Ö distance is 1.9 A. In [Zn(H 2 0) 6 ] 2+ the Zn-H 2 0 distance is 2.15 Ä. of zinc (II) chloride complexes; structure of hydrated non-complexed zinc (II) ion.
	Reference	Z. Naturforsch. 51a, 63—70 (1996); received November 7 1995
	Published	1996
	Keywords	X-ray diffraction, Raman spectra, IR spectra, structures
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	Identifier	ZNA-1996-51a-0063
	Volume	51

34	Author	N.K D, A.K S En, G.	Requires cookie*
	Title	Chemistry of Lanthanons, XLII Preparation and Characterization of Isonicotine and Picoline Hydrazide Complexes of Lanthanons
	Abstract	Rare
	Reference	(Z. Naturforsch. 30b, 769—772 [1975]; received May 5/June 16 1975)
	Published	1975
	Keywords	Earth Complexes, Conductance, Thermal Analysis, IR Spectra
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	Identifier	ZNB-1975-30b-0769
	Volume	30

35	Author		Requires cookie*
	Title	Komplexchemie polyfunktioneller Liganden
	Abstract	, XXXV1 Das Reaktionsverhalten von Co2(CO)8 gegenüber dem tritertiären Phosphin l.l.l-Tris(diphenylphosphinomethyl)äthan Complex Chemistry of Polyfunctional Ligands, X X X V 1 Reaction o f Co2(CO)8 w ith the T ritertiary Phosphine 1,1,1-Tris(diphenylphosphinom ethyl)ethane J o c h e n E l l e r m a n n und J o a c h i m F. S c h i n d l e r Octacarbonyldicobalt reacts with the tritertiary phosphine l,l,l-tris(diphenylphosphino-methyl)ethane (TDPME) to give the ionic complex [Co(CO)2TDPME][Co(CO)4]. Treat ment of [Co(CO)2TDPME][Co(CO)4] with Na[B(CeH5)4], HCIO4 and CH3J yields the
	Reference	(Z. Naturforsch. 30b, 914—919 [1975]; eingegangen am 7. Juli 1975)
	Published	1975
	Keywords	Cobaltcarbonyl Derivatives, Tritertiary Phosphine, Raman Spectra, IR Spectra
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	Identifier	ZNB-1975-30b-0914
	Volume	30

36	Author	Heinrich Homborg, Wilhelm Preetz, Günes Barka, Gernot Schätzel	Requires cookie*
	Title	Darstellung und spektroskopische Charakterisierung von Tetrahalogenooxalato-Osmaten(IY)
	Abstract	Reaction of [OsXe] 2-(X = CI, Br, I) with oxalic acid in water gives the very stable and deeply coloured new complexes [OsX40x] 2-which can be precipitated as alkali or tetra-alkylammonium salts. The salts with long-chain alkylammonium ions are soluble in all common no polar solvents. The IR and Ra spectra and the depolarization ratios are consistent with the local C2v-symmetry. The coupling between the vibrations of co-ordinated oxalate and with the skeletal [OsX402]-modes is apparently small. The optical spectra have been studied at low temperature (10 K). Analogous to [OsXe] 2-the very intense absorptions in the UV and VIS are assigned to the electric dipole allowed electron transfer from "(jr+cr)tiu, 7rt2U(y7), 7it2u(y8) and (<r-f-7r)tiu" to "dt2g". By the descent in symmetry each of these transitions is further split in three components (Ai, Bi, B2) corresponding to the three different groups of ligands, X2 tr -, X2 C -and ox. The distinction between the X2 tr ---Os and X2 C --> Os is caused by a static trans-effect and depends on the difference of the optical electronegativities induced by ox. This splitting is not observed for [OsCLiox] 2 -but is about 900 cm- for [OsBr4ox] 2 -and 1200 cm" 1 for [OsI4ox] 2 -. The well defined bands in the NIR and VIS are assigned to the intraconfigurational d-d-transitions between the spin-orbit components in the octahedral doublegroup Oh* splitted by the lower C2v-symmetry. Some of the zero-phonon transitions within the split of the 3 Tig, Oh-groundstate exhibit extremely high intensities (e~2500 cm 2 /mmol). The assign-ment of these transitions is improved by the electronic Ra spectra. The finestructure of some of the d-d-transitions originates from coupling with Ai vibrational modes especially with Vs(C-O).
	Reference	Z. Naturforsch. 35b, 554—563 (1980); eingegangen am 10. Dezember 1979
	Published	1980
	Keywords	Tetrahalooxalato-osmates(IV) UV-VIS Spectra, IR Spectra, Raman Spectra
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	Identifier	ZNB-1980-35b-0554
	Volume	35

37	Author	Emmanuel Chukwuemeka Okafor	Requires cookie*
	Title	The Metal Complexes of Heterocyclic /?-Diketones and their Derivatives, Part VIII Synthesis, Structure, Proton NMR and Infrared Spectral Studies of the Complexes-Phenyl-3-methyl-4-trifluoroacetyl-pyrazolone-5 (HPMTFP)
	Abstract	of Al(in), Fe(ffl), Co(ffl), Rh(m), In(ffl), and Zr(IV) with l New complexes of Al(III), Fe(III), Co(III), Rh(III), In(III) and Zr(IV) with 1-phenyl-3-methyl-4-trifluoroacetyl-pyrazolone-5, (HPMTFP), have been synthesized and charac-terized by means of elemental analyses, conductivity and magnetic moment measurements, proton NMR and infrared spectroscopy. It is concluded that the ligand, HPMTFP, reacts as a bidentate enol forming neutral metal chelates. The PMR spectra of chelates suffi-ciently soluble in deuterated NMR solvents were recorded and studied. The IR spectra are measured between 4000-200 cm -1 and assignments are proposed for the observed fre-quencies. The M-0 stretching frequency follows the order: AI > Rh > Fe — Co = Zr > In.
	Reference	Z. Naturforsch. 36b, 213—217 (1981); received September 17 1980
	Published	1981
	Keywords	Metal Complexes, PMR Spectra, IR Spectra
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	Identifier	ZNB-1981-36b-0213
	Volume	36

38	Author	Römer, H. Scholl, H. Budzikiewicz, H. Korth, G. Pulverer	Requires cookie*
	Title	A
	Abstract	The structure elucidation of several minor phenazine pigments of Pseudomonads is described. 4-Hydroxyphenazine-l,6-dicarboxylic acid dimethyl ester, 2,3-dihydroxy-phenazine, 2,3,7-trihydroxyphenazine, 4-hydroxyphenazine-l-carboxylic acid, 2,3-di-hydroxyphenazine-l-carboxylic acid, 2,6-dihydroxyphenazine-l-carboxylic acid and 2,3,7-trihydroxyphenazine-l,6-dicarboxylic acid are new phenazine derivatives. The distribu-tion of phenazines in the genus Pseudomonas is investigated.
	Reference	Z. Naturforsch. 36b, 1037—1046 (1981); eingegangen am 27. März 1981
	Published	1981
	Keywords	Phenazines, Bacterial Constituents, Pseudomonads, NMR Spectra, IR Spectra
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	Identifier	ZNB-1981-36b-1037
	Volume	36

39	Author	S. P. Perlepes, ThF. Zafiropoulos, A. K. Anagnostopoulos, A. G. Galinos	Requires cookie*
	Title	Compounds of Complex Halo and Pseudohalo Acids of the Group IIB Metals, Part V [1] Preparative and Spectroscopic Studies of the [Hg2I5]-, [Hg2I6]2-and [Hg3I8] 2 -Ions
	Abstract	The preparations of new compounds, containing the complex anions [Hg2ls] -, [Hg2le] 2-and [Hg3I8] 2 -, are reported. Distorted iodine-bridged configurations are proposed for the complexes in the solid state, utilising analyses, X-ray powder patterns, molar conductance measurements and spectral (IR, UV) data.
	Reference	Z. Naturforsch. 37b, 646—648 (1982); received November 9 1981
	Published	1982
	Keywords	Mercury, Iodomercurates, 3-Picoline, Quinoline, IR Spectra
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	TEI-XML for	default:Reihe_B/37/ZNB-1982-37b-0646.pdf
	Identifier	ZNB-1982-37b-0646
	Volume	37

40	Author	Ulrich Müller, Abdel-Fatah Shihada, Kurt Dehnicke	Requires cookie*
	Title	P(C6H5)4[VOBr4]: Synthese, IR-Spektrum und Kristallstruktur P(C6H5)4[VOBr4]: Synthesis, IR Spectrum and Crystal Structure
	Abstract	PPh 4 [VOBr4] was prepared by the reaction of PPh4Br with VOBr3 in CH2Br2 solu-tion. The structure of the dark violet crystals was determined with X-ray diffraction. PPli4[VOBr4] crystallizes in the space group P4/n with the lattice constants a = 1275.9 and c = 784.5 pm with two formula units per unit cell. The structure type corresponds to the frequently encountered AsPh4[RuNCl4] type. The VOBr4~ ion forms a square pyramid; the V = O bond has a length of 155 pm. In the IR spectrum, the V —O stretching vibration appears at 922 cm -1 .
	Reference	Z. Naturforsch. 37b, 699—701 (1982); eingegangen am 29. Januar 1982
	Published	1982
	Keywords	Tetraphenylphosphonium Tetrabromooxovanadate(V), Synthesis, IR Spectra, Crystal Structure
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	TEI-XML for	default:Reihe_B/37/ZNB-1982-37b-0699.pdf
	Identifier	ZNB-1982-37b-0699
	Volume	37

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