| 1 | Author | Herbert Jacobs, Bernd Harbrecht | Requires cookie* |
| Title | Eine neue Darstellungsmethode für Caesiumhydroxid A New Preparative Method for Cesiumhydroxide  | ||
| Abstract | Cesiumhydroxide has been prepared by the reaction of CsOH • H2O with CSNH2 in super-critical ammonia. Thermochemical data for CsOH are given in the range from 100 to 640 K. The x-ray investigation of the compound above 497.5 K shows a sodium chloride type of struc-ture with a = 6,427 (5) A at 503 K. The lattice constants for the rhombic modification at 298 K are a = 4,350 (3) A, b = 11,99 (1) A and c = 4,516 (3) A. The cell contains four formula units. The structure is of an anii-NaOH type. | ||
| Reference | Z. Naturforsch. 36b, 270—271 (1981); eingegangen am 14. November 1980 | ||
| Published | 1981 | ||
| Keywords | Cesium Compound, Hydroxide, Thermal and Crystal Data | ||
| Similar Items | Find | ||
