| | 1 | Author
| Bernt Krebs, Michael Hein | Requires cookie* | | | Title
| (H502)2SeBr6 4H20 Solvated Halogeno-Chalcogen(IV) Acids, I Preparation and Structure of the Hexabromoselenium(IV) Acid Hydrate (Hs02)2SeBr6 * 4H20  | | | | Abstract
| Hexabromoselenium(IV) acid with the stoichiometric composition H2SeBr6 • 8 H20 is prepared from solutions of SeBr* in concentrated aqueous HBr. If separated from the solution, the crystalline compound is stable only at low temperatures. A single crystal X-ray structure analysis at —100 °C (monoclinic, C2/m, a — 1039.4(5), b = 1028.8(4), c = 836.6(3) pm, ß = 104.11(4)°) shows the acid to contain, besides regular octahedral SeBr6 2 -ions (Se-Br: 255.3(2)-257.9(2) pm), H502+ hydronium ions (0--0: 255(2) pm). The remaining H20 molecules are involved in a hydrogen bond system with O-O: 264(2)-275(2) pm andO-Br: 342(1), 351(1) pm. The formula has to be written as (H502)2SeBr6 • 4 H20. | | | |
Reference
| Z. Naturforsch. 34b, 1666—1670 (1979); eingegangen am 30. Juli 1979 | | | |
Published
| 1979 | | | |
Keywords
| Hexabromoselenium(IV) Acid, Chalcogen Halogen Compounds, Crystal Structure, Hydronium Compounds | | | |
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| default:Reihe_B/34/ZNB-1979-34b-1666.pdf | | | | Identifier
| ZNB-1979-34b-1666 | | | | Volume
| 34 | |
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