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'Hydrogen bonding' in keywords Facet section ZfN Section B [X]

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1	Author	Beatrix Milewski-Mahrla, Hubert Schmidbaur	Requires cookie*
	Title	Synthese und Kristallstrukturen einiger Tetramethylstibonium-Hydrogendicarboxylate Synthesis and Crystal Structures of Some Tetramethylstibonium Hydrogendicarboxylates
	Abstract	Reactions of pentamethylantimony (CH^sSb with carboxylic acids in the molar ratio 1:2 afford one equivalent of methane and essentially quantitative yields of crystalline tetramethylstibonium hydrogendicarboxylates. Six new compounds of this series have been synthesized using benzoic, o-phthalic, salicylic, 4-ethoxy-salicylic, oxalic, and malic acid, and characterized by analytical and spectroscopic data. An ionic structure with strong hydrogen bonds in the anionic components is proposed. The crystal structures of the hydrogen-dibenzoate (1), hydrogen-ortho-phthalate (2) and 4-ethoxy-hydrogen-salicylate (3) were determined by single crystal X-ray diffraction. The compounds can be described as having ionic lattices with some donor-acceptor inter-actions between the stibonium centers and the carboxylate oxygen atoms. The anions are characterized by strong hydrogen bonds O...H...O. Thus, the (CH^Sb-tetrahedron in 1 is distorted by two benzoate oxygen atoms (at 304(2) and 340(2) pm). The cation in 2 is largely undistorted and the anion has a bydrogenpbthalate hydrogen bond of d(O...H...O) = 232 pm. The cation-anion contact in 3 is as short as d(Sb-O) = 289 pm rendering the Sb atom pentacoordinate.
	Reference	Z. Naturforsch. 37b, 1393—1401 (1982); eingegangen am 5. Juli 1982
	Published	1982
	Keywords	Pentamethylantimony, Tetramethylstibonium Salts, Hydrogendicarboxylates, Hydrogen Bonding, X-ray
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	TEI-XML for	default:Reihe_B/37/ZNB-1982-37b-1393.pdf
	Identifier	ZNB-1982-37b-1393
	Volume	37

2	Author	KurtH. Pilgram, LairdH. Gale, GlennE. Pollard	Requires cookie*
	Title	a-hydroxyphostones
	Abstract	The addition-cyclocondensation reactions of three /?-hydroxyketones with four dialkyl phosphites gave 2-alkoxy-3-hydroxy-l,2-oxaphospholane-2-oxides ("a-hydroxyphosto-nes") (7), in moderate yields. In the solid state and in solution, these compounds exist as dimers with hydrogen bonding between the hydroxyl group and the phosphoryl oxygen atom of an adjacent molecule. The crystal and molecular structure of 3-hydroxy-2-methoxy-3,5,5-trimethyl-l,2-oxaphospholane-2-oxide (7 a) has been determined by single-crystal X-ray crystallography: C7H15O4P, monoclinic space group P2-l/n, cell dimensions a = 8.087(1) Ä, b = 13.386(2) A, c = 9.306(1) A, V = 1007.4 Ä 3 , Z = 4, final R = 0.052. The five-membered ring is puckered, with the carbon bearing the OH and CH3 groups lying out of the plane of the remaining four atoms in the ring. The doubly bonded oxygen attached to the phosphorus atom and the hydroxyl oxygen are in a cis-relationship. The 0(l)-0(4) intermolecular bond distance of 2.75 Ä suggests hydrogen bonding. The 0(1)-H(1) intermolecular bond distance of 1.97 Ä is consistent with this conclusion. Thorough synthetic studies have been carried out on intramolecular esters of 3-hydroxyalkane (and alkene) phosphonic and phosphinic acids (phosto-nes [1]). For example, dehydration of 3-hydroxy-alkanephosphonic acids gave phostones of general structure 1 [2] (Table I). Similar phostones, 2 and 3, were obtained from the reactions of 1,3-dihalo-alkanes with phosphonites and phosphinites, re-spectively [3]. At elevated temperature, 3-bromo-alkanephosphonates are converted into phostones 4 [4]. Acyl-lactone rearrangement of a-acetyl-a-diethoxyphosphonylbutyrolactone gave 5 [5]. Unsaturated phostones (8) are obtained by dehydration of the corresponding (3-hydroxy-3-phenyl-prop-2-enyl)phosphonic acids [6]. 3-Hy-droxypropenylphosphonates, prepared by catalytic reduction of 3-hydroxy-l-propynyl-phosphonates, cyclocondense to 9 having potent Cholinesterase inhibitory activity [7]. The reaction of dialkyl 1,2-alkadienylphosphonates with halogens [8-10] and sulfenyl chlorides [12] gave 10. In the reaction of 3-methyl-l,2-butadienephos-phonyl di chloride with halogens, unsaturated tetra-halophostones (11), are formed [13]. The chlorina-tion of 2-methyl-2,3,5-hexatriene-4-phosphonyl di-chloride proceeds similarly in the direction of cyclo-dechlorination to form 12 [14].
	Reference	Z. Naturforsch. 38b, 1122—1129 (1983); received May 6 1983
	Published	1983
	Keywords	X-Ray, Stereochemistry, Hydrogen Bonding, Dimerization
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-1122.pdf
	Identifier	ZNB-1983-38b-1122
	Volume	38

3	Author	Dietrich Mootz, Wolfgang Poll	Requires cookie*
	Title	Fluoride und Fluorosäuren, VI Verbindungsbildung und Kristallstrukturen im System Ammoniak—Fluorwasserstoff [ 1 , 2 ] Fluorides and Fluoro Acids, VI Com pound Form ation and Crystal Structures in the System A m m onia-H ydrogen Fluoride
	Abstract	The melting diagram of the quasi-binary system NH3— HF between the limits NH4HF: and HF was redetermined. The compounds NH 3 • 4H F. NH3 • 5HF and NH3 ■ 8HF with melting points of 26. —14 (dec.) and —95 °C (dec.), respectively, were established as the stable phases. Their crystal structures were determined as those of ammonium hydrogen fluorides NH4[F(HF)3], NH4[F(HF)4] and NH4[HF:(H F)3] • 3HF with extended N -H --F and F -H -F hydrogen bonding.
	Reference	Z. Naturforsch. 39b, 290—297 (1984); eingegangen am 15. September 1983
	Published	1984
	Keywords	System NH3 — HF, Melting Diagram Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/39/ZNB-1984-39b-0290.pdf
	Identifier	ZNB-1984-39b-0290
	Volume	39

4	Author	Christian Robl	Requires cookie*
	Title	Erdalkaliquadratate, VI [1] SrC 4 0 4 -3H 2 0, Typ III Alkaline-earth Squarates, VI [1] SrC 4 0 4 -3H 2 0, Type III
	Abstract	SrC 4 0 4 -3H 2 0, type III, was obtained in an aqueous silica gel besides crystals of SrC 4 0 4 • 3 H 2 0, type I. X-ray crystal structure analysis showed close relationship to BaC 4 0 4 -3H 2 0, but no iso-typism. Sr 2+ is coordinated by four water molecules and four oxygen atoms of the squarate dianion. The connection of Sr 2+ with C 4 0 4 2 leads to layers. The geometry of C 4 0 4 2 is typical for delocalized jr-systems. The O squarate atoms are not equally bound to Sr 2+ . One O squarate atom (0(4)) is bound to two Sr 2+ , two (O(l), 0(2)) are bound to one Sr 2+ , respectively, and the fourth O squaraIe atom (0(3)) shows no bonding contact to Sr 2+ . These differences are compensated for by inter-molecular hydrogen bonds which involve 0(3) three times, O(l) and 0(2) once each, but not 0(4).
	Reference	(Z. Naturforsch. 43b, 99—103 [1988]; eingegangen am 21. September 1987)
	Published	1988
	Keywords	Strontium Squarate Type III, Preparation, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/43/ZNB-1988-43b-0099.pdf
	Identifier	ZNB-1988-43b-0099
	Volume	43

5	Author	Christian Robl	Requires cookie*
	Title	Komplexe mit aromatischen Carbonsäuren, IV [1] Ca 2 [C 6 H 2 (COO) 4 ] * 6 H 2 0 -Eine neue Schichtstruktur Complexes with Aromatic Carboxylic Acids, IV [1] Ca 2 [C 6 H 2 (C00) 4 ]-6H 2 0 -A Novel Layer Structure
	Abstract	Single crystals of Ca 2 [C 6 H 2 (COO) 4 ]-6H 2 0 were grown in aqueous silica gel. Ca :+ hasCN 6+2. The coordination polyhedron is formed by three water molecules and five oxygen atoms of carboxylate groups. Six oxygen atoms are closely bound (235,9—243,9 pm), the two remaining coordination partners are considerably more remote from Ca 2+ (268,2 and 273,8 pm). COO" groups chelate Ca :+ in an asymmetric manner, but the C —O bond lengths do not differ markedly (125,2—126,3 pm). The connection of Ca 2+ with [C,H 2 (COO) 4 ] 4_ leads to rigid layers. Adjacent layers are interlinked by hydrogen bonds. Those oxygen atoms which are weakly bound to Ca 2+ are favoured as proton acceptors in hydrogen bonds. The COO groups are tilted differently against the C 6 -ring plane. One is approximately coplanar, but the other is oriented almost perpen-dicularly.
	Reference	Z. Naturforsch. 43b, 993—997 (1988); eingegangen am 11. April 1988
	Published	1988
	Keywords	Pyromellitate, Layer Structure, Preparation, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/43/ZNB-1988-43b-0993.pdf
	Identifier	ZNB-1988-43b-0993
	Volume	43

6	Author	Crystal, FrankH. Artm Anna, D. Ietrich, M. Ootz, Reinhard Schwesinger	Requires cookie*
	Title	Zur Kristallchemie ungeladener Phosphazen-Basen, I [1] Strukturen zweier Hydrate und eines Acetats von Tris(dimethylamino)methyliminophosphoran
	Abstract	C hem istry o f U ncharged Phosphazene Bases, I [ 1 ] Structures o f Two H ydrates and an A cetate o f T ris(dim ethylam ino)m ethylim inophosphorane Two hydrates and an acetate of the uncharged, very strong phosphazene base tris(dimethylamino)methyliminophosphorane, (Me2N)3P=NMe (for short Me-P]), have been characterized by their crystal structures. A monohydrate, Me-P, • H:0 , mp. 3°C, is monoclinic
	Reference	Z. Naturforsch. 51b, 1369—1374 (1996); eingegangen am 11. März 1996
	Published	1996
	Keywords	Crystal Structure, Hydrate, Hydrogen Bonding, Phosphazene, Uncharged Base
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-1369.pdf
	Identifier	ZNB-1996-51b-1369
	Volume	51

7	Author	Cl Walter, Frank, GuidoJ. Reiß	Requires cookie*
	Title	Spezielle Alkylammoniumhexachlorometallate, II [1] Synthese und Kristallstruktur von Bis(l,2-diammoniopropan)hexachlororhodat(III)-chlorid, [H3N-CH(CH3)-CH2-NH3]2[RhCl6]Cl Alkylammonium Hexachlorometallates, II [1] Synthesis, and Crystal Structure of Bis( 1,2-diammoniopropane) Hexachlororhodate(III) Chloride, (H3N-CH(CH3)-CH9-NH3]-,\|RhCl6]
	Abstract	Bis(1,2-diammoniopropane) hexachlororhodate(III) chloride, [H ^N -CH tCI-fO -CH i-N H ^ [RhCl6]Cl (1) has been obtained by the reaction of rhodium(III) chloride with rac-1,2-diammoniopropane dihydrochloride in hydrochloric acid solution. The quasi-ternary com pound, which crystallizes in the orthorhombic space group Pbca (a -11.0007(13) A, b = 22.181(2) A, c = 14.638(2) A, V = 3571.7(7) Ä \ T = -1 2 0 °C, Z -8) contains two crystallographically independent 1,2-diammoniopropane ions beside one hexachlororhodate and one chloride ion. One of the cations shows a R/S-S/R-disorder of enantiomeric pairs in the centrosymmetric crystal lattice. The packing scheme is determined by a complex framework of hydrogen bonds.
	Reference	Z. Naturforsch. 51b, 1459—1463 (1996); eingegangen am 9. April 1996
	Published	1996
	Keywords	Hexachlororhodate, Alkylammonium Salt, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-1459.pdf
	Identifier	ZNB-1996-51b-1459
	Volume	51

8	Author	Walter Frank, GuidoJ. Reiß	Requires cookie*
	Title	Spezielle Alkylammoniumhexachlorometallate, III [1] Synthese und Kristallstruktur von Tris(guanidinium)- hexachlororhodat(III)-monohydrat, [C(NH2)3 ]3 [RhCl6] * H20 Alkylammonium Hexachlorometallates, III [1] Synthesis, and Crystal Structure of Tris(guanidinium) Hexachlororhodate(III) Monohydrate, [C(NH2)3]3[RhCl6] * H20
	Abstract	Tris(guanidinium) hexachlororhodate(III) monohydrate, [C(NH2)3]3[RhCl6] • H20 (1) has be en obtained by the reaction of rhodium(III) chloride with guanidine hydrochloride in hydrochlo ric acid solution. 1 crystallizes in the triclinic space group P i (o = 7.6013(9) A, b = 8.6912(10) A, c = 15.956(2) Ä, q = 93.177(10)°, ß = 101.691(10)°, 7 = 113.995(9)°, V = 931.8(2), Z = 2). Two crystallographically independent hexachlororhodate ions, three crystallographically independent guanidinium ions and one water molecule are linked by a complex framework of hydrogen bonds.
	Reference	Z. Naturforsch. 51b, 1464—1468 (1996); eingegangen am 9. April 1996
	Published	1996
	Keywords	Hexachlororhodate, Guanidinium Salt, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-1464.pdf
	Identifier	ZNB-1996-51b-1464
	Volume	51

9	Author	Stefan Horstmann, Wolfgang Schnick	Requires cookie*
	Title	Synthese, Kristallstruktur und Eigenschaften von 1,1,3,3,3-Pentaamino- l-th io -l A \3 A 5-diphosphaz-2-en (NH2)2P(S)N=P(NH2)3 Synthesis, Crystal Structure, and Properties of 1,1,3,3,3-Pentaam ino-l-thio-l A5,3A5-diphosphaz-2-ene (N H 2)2P(S)N =P(NH 2)3
	Abstract	(NH2)2P(S)N=P(NH2)3 has been prepared by a two step synthesis. Suitable single crystals were obtained from an acetonitrile solution in a temperature gradient between 60 °C and room temperature. The crystal structure of (NH->)tP(S)N=P(NH->)3 has been determined by single cry stal X-ray methods (P2,/c, a = 9 9 8 .2 7 (9)> '= 762.78(8), c = 1007.70(15) pm, ß = 107.340(7)°, Z = 4). In the crystal structure each hydrogen atom is subject to a hydrogen bond. Four N-H -N hydrogen bonding interactions per molecule build up a framework connecting two molecules in eight-membered rings. Each sulfur atom shows six distances N -H -S in the range of weak hydrogen bonding interactions.
	Reference	Z. Naturforsch. 52b, 490—95 (1997); eingegangen am 18. Dezember 1996
	Published	1997
	Keywords	Aminophosphazenes, Synthesis, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/52/ZNB-1997-52b-0490.pdf
	Identifier	ZNB-1997-52b-0490
	Volume	52

10	Author	Frank Wendland, Christian Näther, Michael Schur, Wolfgang Bensch	Requires cookie*
	Title	Solvothermal Synthesis and Crystal Structure Determination of Tris- (ethyleneamine-ammonium) Tetraselenoantimonat: Non-Centrosymmetry Mediated by an Extended Unusual N-H***N Hydrogen Bonded Network?
	Abstract	The title compound has been synthesized under solvothermal conditions by the reaction of elemental chromium, antimony and selenium in a solution of 40% 1,2-ethanediamine (en) in methanol. The crystal structure consists of tetrahedral SbSe,*3 --anions which are connected by monoprotonated 1,2-ethanediamine (enH+) cations via N-H--Se hydrogen bonding. The enH+ cations are joined via strong N-H -N hydrogen bonds between the ammonium hydrogen and the amino nitrogen atom forming four distinct chains, each built up of three crystallographically independent enH+ cations. Two of these chains are running parallel to [100], the other two are parallel to [010]. Based on this arrangement different centrosymmetric or non-centrosymmetric hydrogen bonding patterns are possible, but only in one chain the sequence of NH2 and NH3+ groups was determined by X-ray diffraction.
	Reference	Z. Naturforsch. 53b, 1144—1148 (1998); received June 15 1998
	Published	1998
	Keywords	Selenoantimonates, Solvothermal Synthesis, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1144.pdf
	Identifier	ZNB-1998-53b-1144
	Volume	53

11	Author	Z. Naturforsch	Requires cookie*
	Title	Hydrogen Bonding of two l-(0-Ammonioalkyl)-2-acyl-cyclopentadienides in the Solid State
	Abstract	A n d re a s M ü ller a n d G e rh a rd M aas The solid-state structures of a l-(0-ammoniopropyl)-2-(2-thienylcarbonyl)-cyclopenta-dienide (2) and a l-(0-ammoniopentyl)-2-(4-methoxybenzoyl)-cyclopentadienide (3) have been determined. Both betaines self-assemble by NH — O hydrogen bonds, but the motifs are different. In the ammoniopropyl case, both intramolecular and intermolecular hydrogen bonds of this type exist, the latter bond being responsible for the formation of infinite chains. In the ammoniopentyl case, intermolecular hydrogen bonds build up a two-dimensional net work which contains centrosymmetric dimers held together by NH • • • 0=C-aryl hydrogen bonds.
	Reference	Z. Naturforsch. 55b, 541—545 (2000); received April 13 2000
	Published	2000
	Keywords	Cyclopentadienides, Hydrogen Bonding, Zw itter Ions
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	TEI-XML for	default:Reihe_B/55/ZNB-2000-55b-0541.pdf
	Identifier	ZNB-2000-55b-0541
	Volume	55

12	Author	Cungen Zhang, Christoph Janiak, Horst Brombacher	Requires cookie*
	Title	Structural Influence of Hydrogen Bonding and ^r-Stacking in fra/is-Diazido-tetra- kis(pyrazole)nickel(II) and rra/is-Diazido-tetrakis(3-methylpyrazoIe)nickel(II)
	Abstract	The molecular nickel complexes fra«s-diazido-tetrakis(pyrazole)nickel(II) and trans-dia-zido-tetrakis(3-methylpyrazole)nickel(II) feature terminal monohapto-bound azide ligands. The pyrazole (pyr) ring planes are aligned along the Nazide-Ni-Nazide axis by intramolecular N-H—Nazide bonds. The crystal packing is controlled by jr-stacking between both pyrazole rings and azide ligands, N -H —Nazide hydrogen bonds, and intermolecular N-H—jrpyr and C-H —N/jrazide interactions.
	Reference	Z. Naturforsch. 56b, 1205—1208 (2001); received July 20 2001
	Published	2001
	Keywords	Nickel Complexes, ^-Stacking, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/56/ZNB-2001-56b-1205.pdf
	Identifier	ZNB-2001-56b-1205
	Volume	56

13	Author	A.N G Arg	Requires cookie*
	Title	Correlation of Mössbauer Quadrupole Splitting ( zI/?q) and Infrared Cyanide Frequency Separation in Alkali Metal Ferricyanides
	Abstract	Mössbauer and infrared spectra of the alkali metal ferricyanides M* [Fe(CN)6] • n H 20 , where M1 = H , Li and N a were studied at room temperature. All the three compounds displayed a doublet with small quadrupole splitting (AEq). Infrared spectra of these compounds in solid state gave two frequencies for C = N stretching vibrations with their separation (Av) in increasing order which was found to be linearly correlated with AEq. A plausible explanation has been given in terms of the interaction of Li+ and Na+ cations w ith the CN-ligands of octahedrally symmetric ferricyanide anion [Fe(CN)6] 3-similar to that of hydrogen atoms which are hydrogen bonded in H 3Fe(CN)6.
	Reference	(Z. Naturforsch. 30b, 96—98 [1975]; received February 1 /September 3 1974)
	Published	1975
	Keywords	Mössbauer Effect, IR Spectra, Ferricyanide Complexes, Hydrogen Bonding, Molecular Structure
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	TEI-XML for	default:Reihe_B/30/ZNB-1975-30b-0096.pdf
	Identifier	ZNB-1975-30b-0096
	Volume	30

14	Author	1h Nm	Requires cookie*
	Title	H-NM R-und IR-spektroskopische Untersuchungen zur Konformation von Hydroxy - methyl-Substituenten in 2.3-Stellung an Hexachlorbicycloheptenen
	Abstract	-an d IR -S pectroscopic C onform ational Studies on H ydro x y m eth y l S u b stitu en ts in th e 2,3 P ositions of H exachlorobicycloheptenes H e l l m u t S i n g e r , I n g o l f S c h u p h a n * u n d K a r l h e i n z B a l l s c h m i t e r Mono Hexachloro-bicycloheptenes and heptadienes with hydroxym ethyl-substituents in the 2 and 3 position show non-equivalence of the methylene protons in their NMR spectra. This is caused both by hindered rotation and the asymmetry of the molecules. For some molecules the spectroscopic data allow conclusions to be made concerning the con formation of the substituents.
	Reference	(Z. Naturforsch. 30b, 373—377 [1975]; eingegangen am 9. Dezember 1974)
	Published	1975
	Keywords	-hydroxymethyl-bicycloheptenes, Bis-hydroxymethyl-bicycloheptenes, Heptadienes, Hindered Rotation, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/30/ZNB-1975-30b-0373.pdf
	Identifier	ZNB-1975-30b-0373
	Volume	30

15	Author	Ger Vos, AnthonieJ. De Kok, GerritC. Verschoor	Requires cookie*
	Title	Complexes of 1,2,4-Triazoles, Part XVII The Crystal Structure of Tris-/«-(4-ethyl-l,2,4-triazole-N l ,N 2 )- (4-ethyl-l,2,4-triazole-N 1 )-aquo-bis [bis(thiocyanato-N)- nickel(II)]hydrate, Ni2(C4N3H7)4(H20)(NCS)4 *H20 (x ~ 2.5)
	Abstract	The crystal structure of Ni2(C4N3H7)4(H20)(NCS)4 • 2.5 H20 has been determined by X-ray diffraction techniques. The compound crystallizes in the monoclinic space group P2i/n with a — 15.121(4), 6= 13.237(2), c= 18.069(3), ß = 94.71(2)° and Z = 4; R = 0.040 (Rm = 0.051). The compound consists of dimeric units in which two Ni ions are bridged by three ethyltriazole (Ettrz) groups. For one Ni, two N donating NCS" groups and an Ettrz coordinating by only one N atom complete the NiNe octahedron. The other Ni atom, which is also octahedrally coordinated, has a coordinated water molecule instead of a monodentate Ettrz.
	Reference	Z. Naturforsch. 36b, 809—813 (1981); received April 2 1981
	Published	1981
	Keywords	4-Ethyl-l, 2, 4-triazole, Binuclear Compound, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/36/ZNB-1981-36b-0809.pdf
	Identifier	ZNB-1981-36b-0809
	Volume	36

16	Author	Dietrich Mootz, D. Agm Ar Boenigk	Requires cookie*
	Title	Fluoride und Fluorosäuren, VII [1] Kristallstrukturen von Säurehydraten und Oxoniumsalzen, XXII [2] Hydratbildung der Trifluoressigsäure sowie Strukturen eines Monohydrats und eines Tetrahydrats [3] Fluorides and Fluoro Acids, VII [1] Crystal Structures of Acid H ydrates and Oxonium Salts, XXII [2] H ydrate Form ation of Trifluoroacetic Acid and Structures of a M onohydrate and a Tetrahydrate [3]
	Abstract	The liquidus and solidus lines of the quasi binary system CF3C O O H —H20 were determined by low temperature difference thermal analysis and the resulting phase relations controlled by X-ray powder diffraction. Formation of a monohydrate and a tetrahydrate, melting congruently at —43 and —16 °C, respectively, is confirmed. In addition a metastable form of the monohydrate and a low temperature form of the tetrahydrate, stable below —47 °C, are indicated. The crystal struc tures of the stable high temperature forms were determined. From these the monohydrate (tetra gonal, space group I42d, Z = 16) is a true acid hydrate, C F ,C 0 0 H H 20 . and the tetrahydrate (triclinic, P I, Z -2) a hydrated oxonium salt, (H 50 2) + [H(CF3COO)2]~ • 6 H:0 .
	Reference	Z. Naturforsch. 39b, 298—3 (1984); eingegangen am 8. November 1983
	Published	1984
	Keywords	Trifluoroacetic Acid, Hydrates, Phase Diagram, Crystal Structure, Hydrogen Bonding
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	TEI-XML for	default:Reihe_B/39/ZNB-1984-39b-0298.pdf
	Identifier	ZNB-1984-39b-0298
	Volume	39

17	Author	Udo Kunze, Hussain Jawad, Wolfgang Hiller, Regina Naumer	Requires cookie*
	Title	Phosphinsubstituierte Chelatliganden, XIV [1] Wasserstoff-Brückenbindung in THF-Addukten von Tetracarbonylchrom-und -molybdänkomplexen mit P,S-koordinierten Phosphinothioformamid-Liganden. Kristallstruktur von [(CO) 4 Cr(PPh 2 C(S)NHMe)] THF Phosphine-Substituted Chelate Ligands, XIV [1] Hydrogen Bonding in THF-Adducts of Tetracarbonylchromium and -molybdenum Complexes with P,S-Coordinated Phosphinothioformamide Ligands. Crystal Structure of [(CO) 4 Cr(PPh 2 C(S)NHMe)] * THF
	Abstract	The tetracarbonyl chromium and molybdenum P,S-chelate complexes la, b and 2a, b are obtained by low-temperature photolysis of the metal hexacarbonyls with the neutral phos-phinothioformamide ligands, Ph 2 PC(S)NHR (R = Me (a), Ph (b)), as stoichiometric 1/1 THF adducts. A weak N-H---O(THF) hydrogen bond is deduced from the ; H NMR spectra which show a collapse of the N-methyl doublet in la (T c -18 °C) but not in 2a. Unusually small P-C(S) couplings are observed in the 13 C{'H} NMR spectra. The N-methyl chromium complex la crystal-lizes in the triclinic space group P1 (Z = 2) with the lattice constants a = 1076.6(3), b = 1235.8(3), c = 915.1(3) pm, a = 97.99(4)°, ß = 92.73(5)°, y = 87.63(5)°. The planar thioamide unit adopts the Z configuration and is linked to the tetrahydrofuran molecule by a hydrogen bond (N-H1-031 164°) with an 0---H contact distance of 191 pm.
	Reference	Z. Naturforsch. 40b, 512—517 (1985); eingegangen am 23. November 1984
	Published	1985
	Keywords	Hydrogen Bonding, THF-Adducts, Phosphinothioformamide Complexes, Crystal Structure, Chromium Complex
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	TEI-XML for	default:Reihe_B/40/ZNB-1985-40b-0512.pdf
	Identifier	ZNB-1985-40b-0512
	Volume	40

18	Author	Christian Robl, Stephanie Hentschel	Requires cookie*
	Title	Zur Kenntnis von Be[C2(C O O )2] * 4 H20 - Ein durch starke Wasserstoffbrückenbindungen stabilisiertes anorganisches Derivat der Acetylendicarbonsäure On Be[C2(COO)2]-4 H 20 -An Inorganic Derivative of Acetylenedicarboxylic Acid Stabilized by Strong Hydrogen Bonding
	Abstract	Colorless orthorhombic single crystals o f Be[C2(COO)2] • 4 H 20 were grown in aqueous silica gel. Space group Cmcm, a = 1004.7(1), b = 675.0(1), c = 1262.4(2) pm, Rg = 0.0264. The crys tal structure consists o f Be(H20)^+ tetrahedra and planar [C2(COO)2]2' anions linked together by strong asymmetric hydrogen bonds. A layer-like arrangement extending parallel (010) made up by [C2(COO)2]2~ anions and hydrogen bound water m olecules o f the Be(H20)^ + tetra hedra is the primary structural feature o f Be[C,(COO)2] -4 H 20 . These layers are stacked and interlinked by coordinative bonds between Be^+ and H 20 to yield a rigid three-dimensional framework. Thermal decom position com m ences with endotherm ic loss o f water o f crystallisa tion at 160 °C followed by several steps o f exothermic degradation yielding finally a soot-like am orphous residue.
	Reference	Z. Naturforsch. 45b, 1499—1502 (1990); eingegangen am 3. Mai 1990
	Published	1990
	Keywords	Beryllium Acetylenedicarboxylate, X -R ay Structure, Thermal Analysis, Hydrogen Bonding
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	Identifier	ZNB-1990-45b-1499
	Volume	45

19	Author	DietrichM. Ootz, Dieter Stäben	Requires cookie*
	Title	Die Hydrate von terf-Butanol: Kristallstruktur von Me3COH * 2 H20 und Me3COH * 7 H20 [ 1 ]
	Abstract	The system /er/-butanol-water has been confirmed by X-ray powder diffraction and single crystal structure analysis to contain two hydrates, a dihydrate and a higher hydrate. The com position o f the latter, contradictory in the literature, could be resolved in favor o f the new one o f a heptahydrate. The dihydrate (m.p. 0.7 °C) is m onoclinic with space group P2, and Z = 2 formula units per unit cell o f dim ensions a = 6.017, b = 6.055, c = 10.377 A and ß -106.60° at -150 °C. The heptahydrate (m.p. -6 °C, dec.) is orthorhombic with space group Pnma, Z = 4, a -12.589, b = 15.251 and c = 6.645 A at -150 °C. Both hydrates contain characteristic layers o f hydrogen-bonded O atom s, which in the heptahydrate are further linked into a three-di-m ensional semi-clathrate structure.
	Reference	Z. Naturforsch. 48b, 1325—1330 (1993); eingegangen am 17. Mai 1993
	Published	1993
	Keywords	te/7-Butanol Hydrates, Melting Diagram, Crystal Structure, Hydrogen Bonding
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	Identifier	ZNB-1993-48b-1325
	Volume	48

20	Author	Dietrich Mootz, Michael Born	Requires cookie*
	Title	Niedere Hydrate von Aminen. Kristallstrukturen der Hemihydrate von Ethyl-und Diethylamin sowie des Hemi-und Monohydrats von 1-Butylamin [1] Lower Hydrates of Amines. Crystal Structures of the Hemihydrates of Ethyl-and Diethylamine and the Hemi-and M onohydrate of 1-Butylamine
	Abstract	The melting diagrams of three systems alkylamine-water have been reexamined and the crystal structures of four lower hydrates determined for the first time. The hydrate EtNH2 -0.5 H20 , m.p. -72 °C, is triclinic with space^roup P 1 and Z = 4 formula units per unit cell of dimensions a = 5.104, b = 8.137, c = 9.394 Ä, a = 100.41, ß = 98.41 and y = 97.96° at -150°C. The O and N atoms are hydrogen-bonded into a two-dimensional array l[ON6/3] analogous to the layer of the Cdl2 structure type. The hydrate Et2NH • 0.5 H20 , m.p. -20 °C, is monoclinic with 12/a, Z = 8 , a -8.324, b = 15.090, c = 10.006 Ä and ß -103.34° at -100 °C. The O and N atoms are linked into a four-membered ring spiro chain ifON^] analogous to that in SiS2. The hydrate l-BuNH2 0.5H20 (m.p. -57 °C, monoclinic, P 2x/c, Z = 8,a = 14.994, b = 5.086, c = 16.15 A .,ß -103.45° at -81 °C) contains essentially the same hydrogen-bonded array as the hydrate EtNH,-0.5H20 (see above). l-BuNH2-H20 , the only monohydrate in vestigated besides the three hemihydrates (m.p. -60 °C, monoclinic, C 2/m, Z = 4, a = 9.68, b = 4.238, c = 15.58 A, ß = 94.9° at -81 °C), has also a two-dimensional H20/N H 2 partial structure, similar to a subset of the three-dimensional network of the adduct NH3 H20 of analogous composition. Z ur Bildung kristalliner Hydrate von einfachen Alkylaminen gibt es eine Reihe von z. T. schon recht frühen Untersuchungen mit allerdings nicht immer eindeutigen und widerspruchsfreien Ergebnissen. Die Bestimmung von Kristallstrukturen be schränkte sich bisher auf einige höhere Hydrate mit W assergehalten oberhalb denen von Pentahydra-ten. Solche wasserreichen Phasen wurden als Cla-thrathydrate oder Semiclathrate charakterisiert. Sie enthalten nämlich dreidimensional vernetzte W irtsstrukturen aus den W assermolekülen und in deren m ehr oder weniger gestörten polyedrischen H ohlräum en die fast immer auch noch H-brücken-aktiven (N -H — O und/oder O -H -N) Am in moleküle als Gastspezies [2]. Gegenstand der vorliegenden A rbeit sind nun erstmals K ristallstrukturen niederer Hydrate von * Sonderdruckanforderungen an Prof. Dr. D. Mootz.
	Reference	Z. Naturforsch. 49b, 243—249 (1994); eingegangen am 27. Oktober 1993
	Published	1994
	Keywords	Amine Hydrates, Lower Hydrates, Melting Diagram, Crystal Structure, Hydrogen Bonding
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	Identifier	ZNB-1994-49b-0243
	Volume	49

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