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'Hydrogen bonding' in keywords Facet   section ZfN Section B:Volume 036  [X]
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1981 (1)
1Author    Ger Vos, AnthonieJ. De Kok, GerritC. VerschoorRequires cookie*
 Title    Complexes of 1,2,4-Triazoles, Part XVII The Crystal Structure of Tris-/«-(4-ethyl-l,2,4-triazole-N l ,N 2 )- (4-ethyl-l,2,4-triazole-N 1 )-aquo-bis [bis(thiocyanato-N)- nickel(II)]hydrate, Ni2(C4N3H7)4(H20)(NCS)4 *H20 (x ~ 2.5)  
 Abstract    The crystal structure of Ni2(C4N3H7)4(H20)(NCS)4 • 2.5 H20 has been determined by X-ray diffraction techniques. The compound crystallizes in the monoclinic space group P2i/n with a — 15.121(4), 6= 13.237(2), c= 18.069(3), ß = 94.71(2)° and Z = 4; R = 0.040 (Rm = 0.051). The compound consists of dimeric units in which two Ni ions are bridged by three ethyltriazole (Ettrz) groups. For one Ni, two N donating NCS" groups and an Ettrz coordinating by only one N atom complete the NiNe octahedron. The other Ni atom, which is also octahedrally coordinated, has a coordinated water molecule instead of a monodentate Ettrz. 
  Reference    Z. Naturforsch. 36b, 809—813 (1981); received April 2 1981 
  Published    1981 
  Keywords    4-Ethyl-l, 2, 4-triazole, Binuclear Compound, Hydrogen Bonding 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0809.pdf 
 Identifier    ZNB-1981-36b-0809 
 Volume    36