| 1 | Author | Yuzo Nishida, Sayo Ito | Requires cookie* |
| Title | Iron(III) Complexes with Hydrogen Peroxide which Can Discriminate Two Reaction Types; Oxidation (H-Atom Abstraction) and Oxygenation Reaction  | ||
| Abstract | Iron(III)-N TA (nitrilotriacetic acid) solution shows high activity for oxidative degradation of 2'-deoxyribose in the presence of hydrogen peroxide, whereas its activity of Fe(III)-T F D A (2-aminomethyltetrahydrofuran-N,N-diacetic acid) is negligible under the same experimental conditions; however the latter solution exhibits abnormally higher reactivity for oxygenation reaction at 8-position of 2'-deoxyguanosine than other iron(III) chelates examined. These results suggest that oxidative degradation of deoxyribose and the oxygenation of deoxy-^uanosine are caused by a different iron(III)-peroxide species. | ||
| Reference | Z. Naturforsch. 50c, 205 (1995); received D ecem ber 14 1994/January 13 1995 | ||
| Published | 1995 | ||
| Keywords | Iron(III) Compounds, Hydrogen Peroxide, Oxidation Reaction Oxygenation Reaction | ||
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