Go toArchive
Browse byFacets
Bookbag ( 0 )
'Hydride Complexes' in keywords
Results  1 Item
Sorted by   
Section
Publication Year
1987 (1)
1Author    Gertrud Weiler, Gottfried Huttner, Laszlo Zsolnai, Heinz BerkeRequires cookie*
 Title    Phosphordonor-substituierte Formylmangan-Komplexe Phosphorous Donor Substituted Formyl Manganese Complexes  
 Abstract    Phosphonomanganese complexes (CH 3 0) 2 (0)PMn(C0)3[P(0CH 3)3] 2 (lb), (CH 3 0) 2 (0)PMn(C0) 2 [P(0CH 3) 3 ] 3 (lc) are obtained via demethylation of the corresponding cationic substituted carbonylmanganese compounds with KHB(secBu) 3 . The reaction of NaBH 4 in methanol with cationic phosphorus donor substituted carbonyl manganese compounds leads to formyl complexes (OC) 3 L 2 MnCHO (L = P(OCH 3) 3 (3a), L = P(OEt) 3 (3c), L -P(0*Pr) 3 (3d), L = PPh 3 (3e)) and (OC) 2 [P(OCH 3) 3 ] 3 MnCHO (3b). 3d decomposes thermally to give an (OC) 3 [P(OzPr) 3 ] 2 MnH and an (0C) 2 [P(0/Pr) 3 ] 3 MnH complex. The latter has been characterized by an X-ray structure determination. 
  Reference    Z. Naturforsch. 42b, 203—209 (1987); eingegangen am 22. August 1986 
  Published    1987 
  Keywords    Formyl, Hydride Complexes, X-Ray 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0203.pdf 
 Identifier    ZNB-1987-42b-0203 
 Volume    42