| 1 | Author | Ursula Bentrup | Requires cookie* |
| Title | Über die thermische Zersetzung von N 2H6[CrF5(H20)] und die neue Verbindung N2H6CrF5  | ||
| Abstract | Thermal decomposition of N 2H 6[CrF5(H 20)] has been investigated by thermoanalytical, X-ray and IR spectroscopic methods. U nder quasi-isobaric conditions the decomposition takes place in several steps. The intermediate N 2H 6C rF 5 has been found which crystallizes monoclinically with a = 555.0 pm, b = 1084.6 pm, c = 777.0 pm,/? = 91.76°. N 2H 6C rF 5 decom poses via an am orphous intermediate to give pure rhomboedrical C rF 3 as the final product. One of the intermediate has been identified as chrom ium fluoride am moniate C rF 3-0.4 N H 3. No hydrolysis reactions have been observed. | ||
| Reference | Z. Naturforsch. 47b, 957—961 (1992); eingegangen am 6. Februar 1992 | ||
| Published | 1992 | ||
| Keywords | Hydrazinium Pentafluorochrom ates(III), Fluorochrom ates(III), Thermal Decomposition, IR Spectra, X-Ray | ||
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