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'Hydrazinium Pentafluorochrom ates III' in keywords
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1992 (1)
1Author    Ursula BentrupRequires cookie*
 Title    Über die thermische Zersetzung von N 2H6[CrF5(H20)] und die neue Verbindung N2H6CrF5  
 Abstract    Thermal decomposition of N 2H 6[CrF5(H 20)] has been investigated by thermoanalytical, X-ray and IR spectroscopic methods. U nder quasi-isobaric conditions the decomposition takes place in several steps. The intermediate N 2H 6C rF 5 has been found which crystallizes monoclinically with a = 555.0 pm, b = 1084.6 pm, c = 777.0 pm,/? = 91.76°. N 2H 6C rF 5 decom­ poses via an am orphous intermediate to give pure rhomboedrical C rF 3 as the final product. One of the intermediate has been identified as chrom ium fluoride am moniate C rF 3-0.4 N H 3. No hydrolysis reactions have been observed. 
  Reference    Z. Naturforsch. 47b, 957—961 (1992); eingegangen am 6. Februar 1992 
  Published    1992 
  Keywords    Hydrazinium Pentafluorochrom ates(III), Fluorochrom ates(III), Thermal Decomposition, IR Spectra, X-Ray 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0957.pdf 
 Identifier    ZNB-1992-47b-0957 
 Volume    47