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'Homocitric Acid' in keywords Facet   Publication Year 1993  [X]
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1993[X]
1Author    G. Erhard, N. Schrauzer, PaulA. Doemeny, JohnG. PalmerRequires cookie*
 Title    The Chemical Evolution o f a Nitrogenase Model, XXII. Reduction of Acetylene with Catalysts Derived from Molybdate, Homocitric Acid and N-M ethylimidazole and a Proposal Concerning the Active Site of Functional Azotobacter Nitrogenases  
 Abstract    Based on model experiments it is suggested that the reduction o f substrates by nitrogenase occurs at a m ononuclear site containing molybdenum, homocitrate and the imidazole com ponent of his-442 o f the apoenzyme, generated from the FeMo-co by a reversible dissociation of the Fe7S8 unit from the M oFe7S8 cluster in a redox-linked process. 
  Reference    Z. Naturforsch. 48b, 1295—1298 (1993); received May 14 1993 
  Published    1993 
  Keywords    Nitrogenase, Acetylene Reduction, M olybdenum-Catalyzed, Homocitric Acid, Histidine, Imidazole 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1295_n.pdf 
 Identifier    ZNB-1993-48b-1295_n 
 Volume    48