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1989 (1)
1Author    Zn, D. Ieter Sellmann, G.Erhard Freyberger, M. Atthias, MollRequires cookie*
 Title    Ubergangsmetallkomplexe mit Schwefelliganden, X LVIa  
 Abstract    -Komplexe mit den zwei-und vierzähnigen Thiolatliganden ,buS2'2-= 3,5-D i(f-butyl)benzol-l,2-dithiolat(2—), S4,2_ = l,2-Bis(2-m ercaptophenylthio)ethan(2—) und buS4,2_ = l,2-Bis(3,5-di(r-butyI)-2-m ercaptophenylthio)ethan(2—) Transition M etal Complexes with Sulfur Ligands, XLVIa Zn, Cd, Hg, Sn, Pb, Bi and Ti Complexes with the Bi-and Tetradentate Thiolato Ligands ,buS2'2-= 3,5-D i(r-butyl)benzene-l,2-dithiolate(2 —), 'S4'2~ = l,2-B is(2-m ercaptophenylthio)ethane(2—) and 'buS4'2~ = l,2-Bis(3,5-di(r-butyl)-2-m ercaptophenylthio)ethane(2—) Thiolato Complexes, M aingroup and Transition Metals Syntheses of neutral 'buS2'-, 'S /-and 'buS4'-and of anionic buS: -complexes with various main group and transition m etals are described. The complexes were prepared by reacting the neutral sulfur ligands or their alkali salts with the metal halide or alkoxide. The ligands coordinate to metal ions in norm al as well as high oxidation states. No redox reactions occur in the latter case. The complexes are usually soluble in organic solvents and were characterized by elem ental analy­ sis and spectroscopic means. 
  Reference    Z. Naturforsch. 44b, 1015 (1989); eingegangen am 12. April 1989 
  Published    1989 
  Keywords    -, Cd-, Hg-, Sn-, Pb-, Sb-, Bi-und Ti 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-1015.pdf 
 Identifier    ZNB-1989-44b-1015 
 Volume    44