| 1 | Author | Joachim Pickardt | Requires cookie* |
| Title | Metallkomplexe mit Hexamethylentetramin als Ligand: Kristallstruktur des Cadmiumiodid-Addukts 3 Cdl2 * 2 C6H12N4 * 4 H20 Metal Complexes with Hexamethylenetetramine as Ligand: Crystal Structure of the Cadmium Iodide Adduct 3CdI2 * 2C6Hi2N4 * 4H20  | ||
| Abstract | The reaction of aqueous solutions of cadmium iodide and hexamethylenetetramine yields crystals of an adduct 3CdI2 • 2CeHi2N4 • 4H20. The crystals are monoclinic, space group P 2i/n, Z = 2, a = 811.5(2), b = 1049.2(4), c = 1849.5(6) pm, ß = 97.73(2)°. The adduct is polymeric and may be regarded as built up from groups of two tetrahedrally and one octahedrally coordinated Cd(II) ions in which the tetrahedra and the octahedron are sharing common iodine atoms at the corners; neighbourirg Cd a units are interlinked by hexamethylenetetramine molecules. | ||
| Reference | Z. Naturforsch. 36b, 1225—1227 (1981); eingegangen am 4. Mai 1981 | ||
| Published | 1981 | ||
| Keywords | Hexamethylenetetramine Complexes, Cadmium Iodide Adduct, Crystal Structure | ||
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