| | 1 | Author
| Rolf Minkwitz, Volker Gerhard, Hans Preut | Requires cookie* | | | Title
| Halogen-Pseudohalogen-Austausch an Bromsulfoniumsalzen. Dimethylthiocyansulfonium-und Dimethylselenocyansulfonium- Hexafluoroarsenat [1] Halide-Pseudohalide Exchange with Bromosulfonium Salts. Dimethylthiocyanosulfonium-and Dim ethylselenocyanosulfonium-Hexafluoroarsenate [1]  | | | | Abstract
| The preparation and spectroscopic characterization o f the sulfonium salts (C H 3)-,SSCN+A sF 6~, (C H 3)2SSeCN + A sF 6~ and (C H 3),S N C O +A sF ^ is reported. The com pounds are obtained via halide-pseudohalide exchange reactions with (C H 3)2SBr+A sF 6~ and the corresponding silver pseudohalide. In addition the crystal structure o f (C H 3)2SS C N +A sF 6~ was determined. The salt crystallizes in the orthorhombic space group Pbca with a = 1048.4(9) pm, b -1290.2(6) pm, c = 1405.1(12) pm and Z = 8. | | | |
Reference
| Z. Naturforsch. 45b, 1625—1631 (1990); eingegangen am 19. März 1990 | | | |
Published
| 1990 | | | |
Keywords
| Raman Spectra, N M R Spectra, Crystal Structure, Bromosulfonium Salts, Hexafluoroarsenate | | | |
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| default:Reihe_B/45/ZNB-1990-45b-1625.pdf | | | | Identifier
| ZNB-1990-45b-1625 | | | | Volume
| 45 | |
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