| | 1 | Author
| J. Beck | Requires cookie* | | | Title
| [TeCl3]+)3[MoCI6]2-(C  | | | | Abstract
| The Reaction o f M oC 14 w ith TeCl4: Synthesis and Crystal Structure of Tris(trichlorotelluronium) H exachlorom olybdate(IV) Chloride, ([TeCl3]+)3[M oCl6]2-[ C l -] Red crystals of (T e C l^ M o C l^ C l) are obtained by reacting MoCl4 with TeCl4 in a 1:3 molar ratio in a sealed evacuated ampoule at 170°. The crystal structure determination (orthorhombic, space group Cmc2), a = 1541.6(2), b = 1268.1(1), c = 1180.6(1) pm) shows the presence of trigonal-pyramidal [TeCl3]+ ions, octahedral [MoCI(l]2-ions, and isolated C l-ions. The ions are linked by long Te-Cl bridges resulting in distorted TeCl(l octahedra. The octahedra are connected by joint edges and corners to zig-zag chains running along the polar c axis. | | | |
Reference
| Z. Naturforsch. 51b, 1127—1131 (1996); eingegangen am 28. Februar 1996 | | | |
Published
| 1996 | | | |
Keywords
| Trichlorotelluronium, Hexachloromolybdate(IV), Synthesis, Crystal Structure | | | |
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| default:Reihe_B/51/ZNB-1996-51b-1127.pdf | | | | Identifier
| ZNB-1996-51b-1127 | | | | Volume
| 51 | |
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