| 1 | Author
| Wolf-Walther Du Mont, Mario Grenz | Requires cookie* | | Title
| Bis(trimethylsiloxy)tin(II): A Heterosiloxane as Soft Ligand  | | | Abstract
| Contrary to earlier reports the reaction of sodium trimethylsilanolate with stannous chlo-ride does not yield bis(trimethylsiloxy)tin(II) (1) but a polynuclear compound of the type Sn20(0SiMe3)2 (2). 1 is obtained from the reac-tion of stannocene with trimethylsilanole. The compound is a dimer that gives rapid exchange reactions of terminal and bridging trimethylsil-oxy groups in inert organic solvents. | | |
Reference
| (Z. Naturforsch. 38b, 113—114 [1983]; eingegangen am 10. September 1982) | | |
Published
| 1983 | | |
Keywords
| Oxastannylenes, Heterosiloxanes, NMR Spectra | | |
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| default:Reihe_B/38/ZNB-1983-38b-0113_n.pdf | | | Identifier
| ZNB-1983-38b-0113_n | | | Volume
| 38 | |
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