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'Heteronuclear Complexes' in keywords Facet   Publication Year 1997  [X]
Facet   section ZfN Section B  [X]
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1Author    LarisaA. Kovbasyuk3, Olga Yu, Vassilyeva3, VladimirN. Kokozay3, Wolfgang LinertbRequires cookie*
 Title    Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dime- thylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis  
 Abstract    A heterotetranuclear C unPbu complex containing 2-dimethylaminoethanol has been synthesized, using copper powder and PbB n as starting materials, and character­ ized by X-ray crystallography. The crystal is composed of centrosymmetric molecules [C uP b B ^ K C H ^N C F b C F L O j^ d m so h . The central strictly planar fragment is a Pb2Ü2 paral­ lelogram completed by bridging oxygen atoms of chelating 2-dimethylaminoethoxo groups. The Pb atom forms four quite short bonds with oxygen atoms of the three 2-dimethylaminoethoxo groups and of the dmso molecule and assumes a six-coordinate structure also involving two bromine atoms. The two oxygen and two nitrogen atoms of two 2-dimethylaminoethoxo groups form the copper coordination environment, which possesses a somewhat distorted square planar geometry. 
  Reference    Z. Naturforsch. 52b, 337—339 (1997); received July 30 1996 
  Published    1997 
  Keywords    Heteronuclear Complexes, Crystal Structure, Direct Synthesis 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0337.pdf 
 Identifier    ZNB-1997-52b-0337 
 Volume    52