| | 1 | Author
| LarisaA. Kovbasyuk3, Olga Yu, Vassilyeva3, VladimirN. Kokozay3, Wolfgang Linertb | Requires cookie* | | | Title
| Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dime- thylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis  | | | | Abstract
| A heterotetranuclear C unPbu complex containing 2-dimethylaminoethanol has been synthesized, using copper powder and PbB n as starting materials, and character ized by X-ray crystallography. The crystal is composed of centrosymmetric molecules [C uP b B ^ K C H ^N C F b C F L O j^ d m so h . The central strictly planar fragment is a Pb2Ü2 paral lelogram completed by bridging oxygen atoms of chelating 2-dimethylaminoethoxo groups. The Pb atom forms four quite short bonds with oxygen atoms of the three 2-dimethylaminoethoxo groups and of the dmso molecule and assumes a six-coordinate structure also involving two bromine atoms. The two oxygen and two nitrogen atoms of two 2-dimethylaminoethoxo groups form the copper coordination environment, which possesses a somewhat distorted square planar geometry. | | | |
Reference
| Z. Naturforsch. 52b, 337—339 (1997); received July 30 1996 | | | |
Published
| 1997 | | | |
Keywords
| Heteronuclear Complexes, Crystal Structure, Direct Synthesis | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0337.pdf | | | | Identifier
| ZNB-1997-52b-0337 | | | | Volume
| 52 | |
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