| | 1 | Author
| HerbertW. Roesky, KaveripatnamS. Dhathathreyan, Mathias Noltemeyer, GeorgeM. Sheldrick | Requires cookie* | | | Title
| Reactions of the Hexafluorothioacetone Dimer with Cyanides of Phosphorus, Arsenic and Germanium  | | | | Abstract
| Cyanides such as P(CN) 3 , As(CN) 3 , PhP(CN) 2 , Bu'As(CN) 2 and Ge(CN) 4 react with [(CF 3) 2 CS] 2 (1) by insertion of the carbon atom of the /so-nitrile isomer into the four-mem-bered [CS] 2 ring to give compounds PR 3 (2), AsR 3 (3), FP(S)R 2 (4), PhP(S)R^ (5), Bu'AsR^ (6) and GeR 4 (7) respectively, where R' is the novel heterocyclic ligand —N=C—S—C(CF 3) 2 —S —C(CF 3) 2 . The crystal structures of 3 and 7 are reported. | | | |
Reference
| Z. Naturforsch. 40b, 240—246 (1985); received September 19/October 25 1984 | | | |
Published
| 1985 | | | |
Keywords
| Crystal Structure, Hexafluorothioacetone, Nitriles, Heterocyclics | | | |
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| default:Reihe_B/40/ZNB-1985-40b-0240.pdf | | | | Identifier
| ZNB-1985-40b-0240 | | | | Volume
| 40 | |
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