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'Heterocycle Phosphorus Nitrogen Compound' in keywords
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1988 (1)
1Author    Uwe Scholz, Mathias Noltemeyer, HerbertW. RoeskyRequires cookie*
 Title    Synthese und Struktur eines ungewöhnlichen Molybdän-Heterocyclus durch Substitution eines Phenylringes in ortho-Stellung Synthesis and Structure of an Unusual Molybdenum Heterocycle by Substitution of a Phenyl Ring in ortho-Position  
 Abstract    The new ligand (Me 3 Si) 2 NC(Ph)NP(Ph) 2 N(SiMe 3) (1) reacts with MOOC1 4 to yield the green metallacycle 4. 4 was characterized by X-ray diffraction. Crystals of 4 are monoclinic, space group P2,/n with a = 1061.2(10). b = 1590.5(10), c = 1737.4(20) pm, ß = 104.84(7)° and Z = 4. Mo is coordinated octahedrally by two nitrogens of the bifunctional ligand. by one oxygen and three chlorine atoms. The ligand undergoes cyclization, a bond being formed between N and one phenylic o-position. 
  Reference    Z. Naturforsch. 43b, 937—940 (1988); eingegangen am 23. März 1988 
  Published    1988 
  Keywords    X-Ray, Molybdenum, Heterocycle Phosphorus-Nitrogen Compound 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0937.pdf 
 Identifier    ZNB-1988-43b-0937 
 Volume    43