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'Heterocumulene Ylide Complexes' in keywords
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1988 (1)
1Author    Heide Lindenberger, Reiner Birk, Olli Orama, Gottfried Huttner, Heinz BerkeRequires cookie*
 Title    Ketenylidentriphenylphosphoran-Komplexe Ketenylidenetriphenylphosphorane Complexes  
 Abstract    Ketenylidenetriphenylphosphorane complexes of the type L"MC(CO)PPh3 L"M = CpMn(CO)2 (2a), CpRe(CO)2 (2b) and Fe(CO)4 (3) are obtained by CO substitution reactions. The synthesis of 3 at 80 °C is accompanied by the formation of a Fe2(CO)6 compound with a bridging a-metallated formyl(triphenylphosphane)carbido ligand. From ethylation of 3 arises an Fe2(CO)6 ferrol-type complex 5. 
  Reference    Z. Naturforsch. 43b, 749—757 (1988); eingegangen am 5. Oktober/22. Dezember 1987 
  Published    1988 
  Keywords    Heterocumulene Ylide Complexes, a-Metallation, Ferroles, X-Ray 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0749.pdf 
 Identifier    ZNB-1988-43b-0749 
 Volume    43