| | 1 | Author
| Matthias Westerhausena, Mathias Kroftaa, Nils Wiberga, Jörg Knizeka, Heinrich Nötha, Arno Pfitznerb | Requires cookie* | | | Title
| Tetrazinn(II)-und Bariumtrizinn(II)-tetrakis[/i3 -tri-ter/-butyIsilylphosphan- diid]-Verbindungen mit einem Tetrametallatetraphosphacuban-Gerüst Tetratin(II) and Barium Tritin(II) Tetrakis[//3-tri-rm-butylsilylphosphandiide] Compounds with a Tetrametallatetraphosphacubane Core  | | | | Abstract
| The metalation o f tri-terr-butylsilylphosphane with bis[bis(trimethylsilyl)amino]stannylen yields nearly quantitatively the tetrameric tin(II) tri-terf-butylsilylphosphandiide with a central Sn4 P4 cubane moiety. Barium bis[tri-/£Tf -butylsilylphosphanide] is accessible via the reaction o f tri-?£T/-butylsilylphosphane with barium bis[bis(trimethylsilyl)amide] in the molar ratio 2 : 1 . This phosphanide reacts with bis[bis(trimethylsilyl)amino]stannylen to give barium tritin(II) tetrakis[/i3-tri-ter?-butylsilylphosphandiide]. Crystallographic data of 1: P 21212), T = 193 K, a = 1532.6(3), b = 2120.2(4), c = 2194.0(5) pm, V = 7.129(3) nm3, Z = 4, R, = 0.0360 (9132 observed data [I > 2a(f)]), wR2 = 0.1064 (all data); crystallographic data of 3: P 2,/c, T= 193 K, a = 1927.35(1), b = 1799.27(2), c = 2201.35(2) pm, ß = 93.010(1)°, V= 7.6234(1) nm3, Z = 4, R, = 0.0321 (11993 observed data [I > 2cr(/)]), wR2 = 0.0772 (all data). | | | |
Reference
| Z. Naturforsch. 53b, 1489—1493 (1998); eingegangen am 3. Juli 1998 | | | |
Published
| 1998 | | | |
Keywords
| Arene Complexes, Barium, Heterocubanes, Phosphorus, Tin | | | |
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| ZNB-1998-53b-1489 | | | | Volume
| 53 | |
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